-
Fire spread by convection is mostly in _____ direction
Upward
-
Heat can travel where ___ does not exist
Matter
-
Radiant heat is one of the major sources of fire spread to
Exposures
-
Generally the ____ process requires less heat input than does the _____ process
Vaporization - Pyrolysis
-
The degree of fuel flammability is determined by
Characteristics of the fuel, including shape and size, position, density, water solubility, reactivity, and volatility
-
MSDSs contain specific information on characteristics for materials that are considered hazardous. What are these characteristics ?
shape and size, position, density, water solubility, reactivity, and volatility
-
Vapor density is a concern with?
Volitile liquids and gaseous fuels
-
Most flammable liquids have a specific gravity of
Less than one
-
Liquid fuels with flash points greater than waters boiling point (212) react ____ to water and foam extinguishment applications
Violently
-
Water boils on contact with hot fuel causing a dangerous frothover condition when ____ are encountered
Fuel tank fires
-
The higher the vapor pressure of a liquid the greater the rate at which it _____ and the lower it's ____ becomes.
Evaporates, boiling point
-
The flash point is the___of the fuel
LFL
-
The spread of fire in an open area is primarily due to heat energy transmitted from the ____ to nearby ___.
Plume, fuels
-
Fire spread in outside fires is increased by ____ and ____ , which allows exposed fuels to _____.
Wind, a sloping surface, preheat
-
When the gases reach the ceiling, the ceiling covering materials absorb heat energy by
Conduction
-
The growth stage continues as long as there is sufficient
Fuel and oxygen and available
-
Compartment fires in the growth stage are usually ____ controlled
Fuel
-
Temperature range of flashover is approximately
900 to 1200
-
Ignition temperature of carbon monoxide
1128°F or 609°C
-
Flashover temperature range correlates with the ignition temperature of
Carbon monoxide
-
One of the most common gases released by pyrolysis (sublimation)
Carbon monoxide
-
During this period, The burning fuels are releasing the maximum amount of heat possible and producing large volume of unburned fire gases
Fully developed
-
Rollover AKA
Flame over AKA
-
Occurs when flames move through or across unburned fire gases during a fires progression
Rollover (flameover)
-
Rollover is distinguished from flashover because
Only the gases are burning in roll over, not the entire contents of the compartment
-
What structural members retain heat for a long time following extinguishment
Concrete and steel
-
Fire in a confined compartment or structure has two particularly important characteristics what are they ?
Limited amount of oxygen and the fire gases released are trapped and build up
-
Factors that impact the development of a fire in a compartment :
- 1. Size and # of vent openings
- 2. Volume
- 3. Height
- 4. Size and location of the first fire group
-
The plumes of burning fuel in the center of a compartment ?
Entrain more air and thus are cooler than those aginst the ceiling or in the corners
-
The temps that develop in a compartment are the direct result of the ?
Energy released as the fuels burn
-
The heat rising in a fire plume is transported by
Covection and radiation
-
As the hot gases travel over surfaces of other fuels in the compartment, heat is transferred to them by
Conduction
-
Factors that effect the development of a fire outside a compartment are
- 1. Wind direction and velocity
- 2. Relative humidity
- 3 terrain and slope
- 4. Size composition, and location of the fuel package that is first ignited
- 5. Availability and locations of additional fuel packages (target fuels)
-
In an exterior fire what determines the amount of heat generated ?
The quanity, type, and physical makeup of the primary fuel source
-
What are the products of combustion ?
Heat, light, smoke, fire gases, and flame
-
In an exterior fire Wind direction and velocity determine?
Fire-suppresion attack tactics and extinguishing agent choices
-
Large transformer oil capacity
20,000-25,000 gallons
-
Smaller vaulted or subterranean transformers oil capacity
300-20,000 gallons
-
What is the only way to extinguish a smoldering fire
Cooling
-
Water extinguishes fire either through
Cooling (or quenching) or smothering
-
The advantages of water that are extremely valuable for fire extinguishment are
- 1. Readily avalible and in expensive
- 2. Greater heat absorbing capacity than other extinguishing agents
- 3. Large amount of heat required to turn ro steam
- 4. Greater the surface area the more heat is absorbed
-
At normal temp _____ water exist in a liquid state
32°-212°
-
Smothering is accomplished when the. Expansion of steam
Reduces oxygen in a confined space
-
Disadvantages of water
- 1. Reignition barrier
- 2. Low viscocity
- 3. Absorbsion
- 4. Reacts w/ some materials
- 5. Collapse from weight
- 6. May spread flammable liquids when they float on waterw surface
- 7. Runoff
- 8. Electrocution hazard
- 9. Freezes. Requires anti freeze
-
Class D materials are particularly hazardous in?
Powdered forms
-
Medium expansion foam most commonly used at a rate of 20:1 to 200:1 through
Hydralically operated nozzle-style delivery devices
-
Most modern foam concentrates may be stored for long periods of time in excess of
10 years
-
Optimum storage life can be achieved by ?
Following manufacturers recommendations onfoam concentrate storage containers and there related enviormental conditions
-
To prevent corrosion on metal parts, pumps, hoselines, proportioners, and nozzles flush with____ . Always ____ moving parts of ___,____, and____ after using foams.
1. Clean water following each use of foam
-
____ are all compatible with CO, halon substitute, and dry chemical agents and may be ___ _____ with them.
- 1. AFFF, FFFP, and Fluoroprotein foams
- 2. Simultaneously discharged
-
Using foam , halon substitute , and dry chemical agents together is commonly known as
Multiagent attack
-
Several different types of special apparatus are used for multiagent applications ranging from ?
Small cart-mounted units commonly found in industrial facilities to large ARFF VEHICLES.
-
The biodegradability of foam in either solution or concentrate form is determined by:
The rate at which environmental bacterias dissolve or degrade (break down) the foam.
-
Where AFFF concentrate is concerned, environmental issues revolve around
Glycol ethers (AKA butylcarbitol) and perfluorooctylsulfonates (PFOS).
-
Some AFFF concentrates use _______ as a water-dispersing solvent and
Butylcarbitol
-
refractive index tracker is used to determine
The concentration of the finished foam when it has been aplied to a fuel.
-
EPA determined that both ____and____ might be hazardous to the environment
Glycol ethers and PFOS
-
Elements that affect the drainage process ?
Fuel temp, heat of the fire, size of the flame front, and to a lesser extent, ambient air temp and wind.
-
Thick and viscous concentrates are typically
AR-AFFF
-
Thinner concentrates are generally found in the
non-alcohol resistant AFFF FFFP AND FLUOROPROTEIN FOAM Or class A foams
-
____ and ____ tend to be fast drainers that spread rapidly across liquid fuel surfaces
AFFF and FFFP
-
Class A concentrate is a formulation* of
Hydrocarbon surfacants
-
Shelf life of class A concentrate
Indefinite
-
Class A foam is used in ___ percentages harm to the environment is ___ concern under ordinary conditions. Take care to prevent direct discharge of concentrates into ___and___
- 1. Small
- 2. Not
- 3. Public or private waterways
- 4. Sanitary sewer systems
-
Characteristics that affect class A foam ? (6)
- 1. Surface tension reduction
- 2. Expasion
- 3. Drainage
- 4. Consistency
- 5. Retention
- 6. Viscocity
-
Consistency is an important cideration when establishing class A foam
Delivery to a fire
-
Class A foam does not adhere to?
Hot, fuel surfaces in excess of 212° F
-
Affects retention time for class A foam :
Air temp, wind movement, fuels latent heat, and the amount of heat present
-
Class A foam concentrates are mixed in proportions of
.01% to 1%
-
Most foam nozzles produce more stable finished foams at a ___ % concentration than they do at ___% to ___% concentrations
-
Employing %s greater than ___ with standard fog nozzles does not appear to increase fire-fighting performance
.5
-
Exposure protection may be enhanced w/ class A foam through ___ at ___ proportioning settings
- 1. Fog nozzles
- 2. 1% or greater
-
Common guidelines for class A foam concentrate proportioning: attack and overhaul with standard fog nozzles
.2% -.5%
-
Common guidelines for class A foam concentrate proportioning: Exposure protection with standard fog nozzles:
.5%-1%
-
Common guidelines for class A foam concentrate proportioning: Most operations with air-aspirating foam nozzles-
.3%-1%
-
Common guidelines for class A foam concentrate proportioning: Most operations with CAFS
.2%-.5%
-
With ___ finished foam, a strong need to adjust the air and concentrate ratio is present
Medium
-
The use of class A foam in finished or ___ can play a major role in extinguishing deeply concentrated fires
Plain solution forms
-
Exposure protection may be enhanced with applying class A foam through fog nozzles at ?
1% or greater proprtioning settings
-
Class B finished foam may be proportioned into the fire stream via
Fixed system, apparatus mounted system, or portable foam proportioning equipment
-
CLASS B
The foam may be applied either with standard fog( ___ and___) or with air aspirating foam nozzles (___)
- 1. AFFF and FFFP
- 2. ALL KINDS
-
___ listed AFFF must pass more stringent test than ___listed AFFF
-
Freeze protected AR-AFFF concentrates may not be ___ because the antifreeze additives tend to ___?
- 1. UL-listed
- 2. Reduce the effectivness of finished foam
-
To be effective, a good class B foam must contain the right lend of the following characteristics:
- 1. Water retention
- 2. Finished foam life
- 3. Heat resistence
- 4. Multiporpose use
- 5. Viscosity
- 6. Knockdown speed and flow
- 7. Fuel resistence
- 8. Vapor surpresion
- 9. Alcohol resistance
- 10. Quarter life
-
Water retention properties of finished foam are the keys to
Characteristics of good class B foams: Long-life vapor supresion
-
The life of finished foam is affected by
heat, type of concentrate, expansion ratio, fuel involved, and environmental conditions.
-
Most finished foam breaks down when the fuel's temp is near or over
212°F
-
foam breaks down rapidly as the fuel temp rises and will perhaps become ineffective when the fuels temp is near or over
150°F
-
Highly viscous liquid concentrates are very thick and difficult to proportion through some types of foam pumps. Typically these viscous foams are?
FFFP
-
Foams with high fuel resistance can be used for
Fixed system subsurface injection into storage tanks
-
___,___,and___foams poses a fuel resistance that prevents contamination of the foam
AFFF, FFFP, Fluoroprotein
-
___,___,and___foams have little or no fuel resistance
Regular protein, high-expansion, and class A
-
Alcohol resistant foam concentrates are formulated to protect the finished foam by providing a
Barrier (membrane) between the fuel and finished foam
-
Quarter-life is the time required in minutes for ___ of the total liquid solution to drain from the finished foam
1/4
-
1% AR foams are available for use on hydrocarbon spill fires using
Type III application devices and procedures
-
Type III devices may include
Foam connon or handheld nozzles
-
When employing AFFF, FFFP, or AR-AFFF solution on a hydrocarbon spill fire, the discharge rate should equal
10% of the area of a spill
-
Once the fire is extinguished, finished foam consumption is only affected by the
Latent heat of the fuel,weather, and natural drainage rate
-
Medium and high-expansion foam concentrates are used in large volumes for
Vapor suppresion or to flood confined spaces
-
Although rare, May still be found in a fixed fire-suppression system
Regular protein foam concentrste
-
Regular protein generally has ___ heat stability, it is not as mobile or fluid as ___ or ___ is___ fuel pickup available in __ and __ % concentrations __ water retention capabilities __ heat resistance performance ___ affected by freezing an thawing store at temp range from __to__. freeze protection ?__
dry chemical compatible?
Used on ?
- 1. Very good
- 2. Synthetic-based or modern fluoroprotein
- 3. Very suseptable
- 4. 3 and 6
- 5. Exellent
- 6. High
- 7. Can be
- 8. 35° to 120°
- 9. Yes
- 10. No
- 11. Only hydrocarbons
-
Fluoroprotein foam combination of ___ and ___
Protein and synthetic
-
Oleophobic (oil shedding)
Fluoroprotein foam
-
When fluorinated surfactant was added to detergent foam concentrates, the water that drains from foam blanket floated on jet fuel this known as
Auqueous film
-
The most commonly used foam today
AFFF
-
Completely synthetic, consist of fluorochemical and hydrocarbon surfacants combined with high boiling point solvents and water
AFFF
-
Pre mixable in portable extinguishers and water tanks
AFFF
-
Stores at temperatures ranging from 25°-120°
AFFF
-
When applied to polar solvent fuels they create a membrane
AR-AFFF
-
high heat resistance
- Regular protein
- FFFP
- FLUORO PROTEIN
-
-
Can be Plunged into fuel
AR-FFFP
-
Good low temp viscosity
AFFF
-
Designed solely for use on unignited spills of hazardous liquids
Vapor-mitigating
-
Poor heat resistance because the air-to-water ratio is very high
High expansion
-
Wheather the finished foam is high or med is determined by the type of
Application device used
-
High expansion foam has three basic applications
- 1. Concealed space
- 2. Fixed-extinguishing systems
- 3. Class A applications
-
Suitable for subsurface injection
- AR-FFFP
- AFFF
- AR-AFFF
- REGULAR PROTEIN
-
Available in 3-6% concentrations
- Fluoroprotein
- FFFP
- REGULAR PROTEIN
-
Performance not affected by freezing or thawing
- Fluoroprotein
- FFFP
- HIGH EXPANSION
-
Stores between 35°-120°
- Fluoroprotein
- FFFP
- HIGH EXPASION
- REGULAR PROTEIN
-
Comparable with dry chem.
-
For use with fresh or salt water
-
Does not work effectively with water-soluble or water Miscible
Emulsifiers
-
Slow draining foam blankets are desirable when
Long-term vapor suppresion is desired
-
Uses a foam eductor, inductor, line proportioner, or ratio controller
Eduction (induction)
-
Uses a foam-concentrate pump or bladder proportioner to pump foam concentrate at the appropriate ratio into a water stream
Injection
-
Uses a "dump and pump" or one time use process
Batch mixing
-
Stores in a solution ready to use. One of the more commonly used methods of proportioning
Premixing
-
Uses an external pump or head pressure to force foam concentrate Into the fire stream at the right ratio for the flow desired
Injection
-
Simplest method of mixing foam. Is commonly used to mix foam concentrates within a fire apparatus water tank
Batch mixing
-
Commonly practiced with class A foam and can be done with all concentrate except AR-AFFF
Batch mixing
-
"dump and pump"
Batch mixing
-
One of the most commonly used methods of proportioningl
Premixing
-
This type of proportioning is Typically used with portable fire extinguishers, skid-mounted multiagent extinguishers, wheeled fire extinguishers, and vehicle mounted tank extinguishing systems
Premixing
-
____ concentrate is particularly prone to evaporation
AR-AFFF
-
IBC range in capacity from ?
- 250-450 gallons
- Depending on the manufacturer
-
Tank capacities for foam tankers are:
1,500 to 8,000
-
These vehicles may be built on a straight frame with tandem rear axles or as tractor trailers
Foam tenders
-
Foam concentrate tanks are found on
Municipal and industral fire and emergency service pumpers, foam tenders, and ARFF APPARATUS
-
Foam concentrate tanks on pumpers range from
20-200 gallons
-
ARFF apparatus may carry concentrate in excess of
600 gallons
-
Apparatus foam tanks must be fitted with ___ and ___ to Prevnet evaporation.
Airtight tank lids and vacuum/pressure vent
-
AR-AFFF ISA PARTICULAR CONCERN IT HAS ___ RATHER THAN A _____ IN IT'S FORMULATION AND IS PRONE TO _______
- Water
- Dispersing solvent
- Evaporation
-
Fixed fire suppression system tanks sizes vary but tanks in exceeds of ___ are common
3,000 gallons
-
Storage tank-size variables include the following:
- • size or capacity of the foam fire-supression system
- • hazard being protected
- • discharge duration required for extinguishment
-
On-site storage tanks usually have ____ and ____ that permit the refilling of apparatus tanks from above this type of system takes the place of ____ filling
- • Permanent transfer pumps and overhead piping
- • ground level
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