-
Entropy
- The tendency towwards randomness
- the more disordered the system, the higher the entropy
-
Energy
the ability ot do work, to move matter
-
Potential energy
- Stored energy available to do work
- A baseball player about to throw a ball
-
Kinetic energy
- energy being used to do work
- Any mkoving object possesses this
- The soaring baseball
-
Calorie
the amount of energy required to raise the temp. of 1 gram of water from 14.5 degrees C to 15.5 degrees C
-
Kilocalorie
- The most common unit for measuring the nergy content of food and the heat output of organisms
- The energy required to raise the temp. of a kilogram of water by 1 degree C
- 1 kilocalorie=1000 calories
-
Thermodynamics
- The syudt of energy transformations
- The laws regulate the energy conversions vital for life, as well as those that occur in the nonliving world
- They apply to all energy transformations
-
First law of thermodynamics
- The law of energy conversion
- Energy cannot be created or destroyed but only converted into other forms
- The total amount of energy is constant
-
Second law of thermodynamics
- all energy transformations are inefficient because every reaction loses some energy to the surroundings as heat.
- You will always lose some energy as heat with every chemical reaction
- Also says that organisms can increase in complexity as long as something else decreases in complexity by a greater amount
-
Metabolism
- The biochemical reactions of a cell
- Includes all of the chemical reactions in cells, including those that build new molecules and those that break down existing ones
-
Metabolic pathways
- When the product of one reaction becomes the starting point, or substrate, of another
- Enzymes enable metabolic reactions to procedd fast enough to sustain life
-
endergonic reaction
- 1 type of metabolic reaction
- Requires an input of energy to proceed
- the products contain more energy that the reactants
- Tend to build complex molecules from simpler components
- Example- a disaccharide having more energy than its individual monosaccharides-->the reactants must have absorbed energy from its surroundings
-
Exergonic reaction
- 1 type of metabolic reaction
- Releases energy
- The products contain less energy than the reactants
- Example-cellular respiration-the breakdown of glucose to carbon dioxide and water
-
Chemical equilibrium
- the reaction goes in both directions at the same rate
- Does not always mean that amounts are equal
- The rate of formation is equal
-
Oxidation-reduction (redox) reactions
- Energy transformation- transfer energized electrons from one molecule to another
- Oxidation and reductions occur simultaneously b/c if one molecule is reduced (gains electrons), then another must be oxidized (loses electrons)
-
Oxidation
- the LOSS of electrons from a molecule, atom, or ion.
- Adding oxygen because that is strongly electronegative, which attracts electrons away from their original atom
- release energy as they degrade complex molecules into simpler products
-
Reduction
- the GAIN of electrons
- require a net input of energy
-
Electron transport chains
- When groups of cytochromes align in membranes with other proteins, they form these
- each protein accepts an electron from the molecule before it and passing an electron to the next
- Small amounts of energy are released at each step of an electron transport chain, and the cell uses this energy in other reactions
-
ATP
- AKA adenosine triphosphate
- Temporarily stores much of the released energy of life
- A go-between molecule that holds the energy released in exergonic reactions, and then applies it to the endergonic ones
- Structurally similiar to a nucleotide
- All cells depend on ATP to power metabolism and many other cellular activities
-
Coupled reactions
simultaneous reactions in which one provides the energy that drives the other
-
Phosphoroylating
- How a cell uses ATP as an energy source
- The transfer of its phosphate group to another molecule
- Can energize the target molecule, making it more likely to bond w/ other molecules-->ATP fuels endergonic reactions
- Can also change in the shape of the target molecule
- Uses these changes to move substances throughout the cell
-
Enzyme
- A protein that catalyzes (speeds) a chemical reaction without being consumed
- Usually either dismantle or build other molecules
- copy DNA, build proteinsdigest food, and recycle a cell's worn out parts
- Work faster as the temp increases, but only to a limit
- Drugs and poisons can inhibit function
-
Energy of activation
- The amount of energy required to start a reaction
- Initial energy kick
- By reducing the energy activation, some enzymes increase reaction rates a billion times
-
The enzyme's active site
- the region to which the reactants (substrates) bind
- The active site does not fit like a key in lock, but contorts slightly
-
Cofactors
- Nonprotein helpers
- Substances that must be present (with also water and substrates) for an enzyme to catalyze a chemical reaction
- Usually oxidized or reduced during the reaction
- Not consumed-->return to their original state when the reaction is complete
- Coenzymes=organic cofactors
-
Negative feedback
- An excess of a reaction's product inhibits the enzyme that controls its formation
- When the product level falls, the pathway resumes its activity
- A thermostat shuts AC off when it's too cold
-
Noncompetitive inhibition
- When product molecules bind to the enzyme at a site other than the active site, but in a way that alters the shape of the enzyme so that it can no longer bind substrate
- Does not compete to occupy the active site
-
Competitive inhibition
- The product of the reaction binds to the enzyme's active site, preventing it from binding substrate
- The product competes with the substrate to occupy the active site
-
Positive feedback
- When a product activates the pathway leading to its own production
- Example- blood clotting
-
Concentration gradient
- A solute is more concentrated in one region than in a neighboring region
- Tea bag- water is darker around the tea bag
-
Passive transport
- When a substance moves across a membrane without the direct expenditure of cellular energy
- Involves diffusion
-
Diffusion
- the spontaneous movement of a substance from a region where it is more concentrated to a region where it is less concentrated.
- Does not require energy input
-
Simple diffusion
- a form of passive transport in which a solute moves dowm its concentratiobn gradient w/o the use of a carrier molecule
- Ex- lipids, O2, CO2,
-
osmosis
the simplle diffusion of water across a biological membrane
-
Isotonic
- The plasma's solute concentration is the same as the inside of the red clood cell
- Water doesn't flow in or out of the cell
- Has normal doughnut-shaped form
-
Hypotonic
- concentration of solutes is lower than inside the cell
- Water will enter a red blood cell immersed in pure water
- The cell may burst
-
Hypertonic
- higher concentration of solutes than the cell's cytoplasm
- Cell shrivels and may die for lack of water
-
Turgor pressure
- The resulting force of water against the cell wall
- Wilted flower demonstrate lost turgor pressure
-
Facilitated diffusion
- A form of passive transport in which a membrane protein assists the movement of a polar solute along its concentration gradient
- Does not require energy expenditure
- Ex- glucose moves into red blood cells through this process
-
Active transport
- A cell uses a transport protein to move a solute against its concentration gradient- from where it is less concentrated to where it is more
- energy to drive this process comes from ATP
-
Sodium-Potassium pump
Uses ATP as an energy souce to expel 3 sodium ions for every 2 potassium ions it admits
-
Endocytosis
Allows a cell to engulf fluids and large molecules and bring them into the cell
-
Phagocytosis
The cell captures and engulfs large particles, such as debris or even another cell
-
Exocytosis
- Opposite of endocytosis
- Uses vesicles to transport fluids and large particles out of cells
|
|