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Synthesis of Epoxides
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R-CH=CH-R +
MCPBA
->
epoxide
R-CH=CH-R +
C
6
H
5
CO
3
H
->
epoxide
R-CH=CH-R + (
HO
3
C-C
6
H
5
-COO
-
)Mg
2+
->
epoxide
R-CH=CH-R --> epoxide (3 answers)
MCPBA (Cl-C
6
H
5
-CO
3
H)
peroxybenzoic acid (C
6
H
5
-CO
3
H)
MMPP ((HO
3
C-C
6
H
5
-COO
-
)Mg
2+
)
alkene +
X
2
, H
2
O
->
halohydrin R-CH(Br)-CH(OH)-R
halohydrin R-CH(Br)-CH(OH)-R +
NaOH
->
epoxide
halohydrin R-CH(Br)-CH(OH)-R --> epoxide
NaOH
Br-CH
2
-CH(OH)-R +
2,6-dimethyl pyridine, 2,6-lutidine
->
epoxide
Br-CH
2
-CH(OH)-R --> epoxide
2,6-dimethyl pyridine and 2,6-lutidine
Author
enger91
ID
85240
Card Set
Synthesis of Epoxides
Description
University of MN twin cities, CHEM 2302
Updated
2011-05-11T19:37:16Z
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