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Synthesis of Ethers
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Williamson Ether Synthesis
R-OH
NaH
-> R-O
-
primary alkyl halide-
> R-O-R
R-OH
NaH
->
R-O
-
R-O
-
R-OH + TsCl, pyridine
->
R-O-R
Alkoxy Mercuration
R-CH=CH-R
1) Hg(OAc)
2
, R-OH 2) NaBH
4
-> R-O-R
R-OH
heat, H
2
SO
4
->
R-O-R
R-O
-
--> R-O-R (Williamson Ether Synthesis)
primary alkyl halide
R-CH=CH-R --> R-O-R (alkoxy mercuration)
1) Hg(OAc)
2
, R-OH
2) NaBH
4
Author
enger91
ID
85214
Card Set
Synthesis of Ethers
Description
University of MN twin cities, CHEM 2302
Updated
2011-05-11T17:47:44Z
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