A homogeneous mixture of two or more substances in a single phase
Solvent
the dissolving medium in a solution
Solute
The substance dissolved in a solution
Suspension
When the particles are so large that they settle out unless the mixture is constantly stirred or agitated
Colloids
Particles that are intermediate in size between those in solutions and suspensions
Tyndall Effect
When light is scattered by the particles in a colloid
Electrolyte
A substance that dissolves in water to give a solution that conducts electric current
Nonelectrolyte
A substance that dissolves in water to give a solution that does not conduct electricity
Factors Affecting Rate of Dissolution
1) Increasing that surface area of the solute
2) Agitating a solution
3) Heating a solvent
Solution equilibrium
The physical state in which the opposing processes of dissolution and crystallization of a solute occur at equal rates
Saturated Solution
A solution that contains the maximum amount of dissolved solute
Unsaturated Solution
A solution that contains less solute than a saturated solution
Supersaturated Solution
A solution that contains more dissolved solute than a saturated solution under the same conditions
Solubility
The amount of that substance required to form a saturated solution with a specific amount of solvent at a specified temperature
Hydration
The solution process with water as the solvent
Immiscible
Liquids that are not soluble in each other
Miscible
Liquids that dissolve freely in one another in any proportion
Henry's Law
The solubility of a gas in a liquid is directly proportional to the partial pressure of that gas on the surface of the liquid
Effervescence
The rapid escape of a gas from a liquid in which it is dissoleved
Solvated
A solute particle that is surrounded by solvent molecules
How does pressure affect solubility?
Little change in liquid or solid solubility, but increases solubility in gases
How does temperature affect solubility?
An increase in temperature decreases the solubility of gases, but mostly increases the solubility of solids in liquids
Enthalpy of solution
The net amount of energy absorbed as heat by the solution when a specific amount of solute dissolves in a solvent
Concentration
A measure of the amount of solute in a given amount of solvent or solution
Molarity
The number of moles of solute in one liter of solution
Molality
The concentration of a solution expressed in moles of solute per kilogram of solvent
Dissociation
The separation of ions that occurs when an ionic compound dissolves
Net Ionic Equation
Includes only those compounds and ions that undergo a chemical change in a reaction in an aqueous solution
Spectator Ions
Ions that do not take part in a chemical reaction and are found in solution both before and after the reaction
Ionization
Ions are formed from solute molecules by the action of the solvent
Strong Electrolyte
Any compound whose dilute aqueous solutions conduct electricity well; this is due to the presence of all or almost all the dissolved compound in the form of ions
Weak Electrolyte
Any compound whose dilute aqueous solutions conduct electricity poorly; this is due to the presence of a small amount of the dissolved compound in the form of ions
Colligative Properties
Properties that depend upon the concentration of solute particles but not on their identity
Nonvolatile Substance
One that has little tendency to become a gas under existing conditions
Colligative Properties (3)
1) Vapor-pressure lowering
2) Freezing-point depression
3) Boiling-point elevation
Molal Freezing-Point Constant (Kf)
The freezing-point depression of the solvent in a 1-molal solution of a nonvolatile, nonelectrolyte solution (1.86 C for water)
Freezing-Point Depression
The difference between the freezing points of the pure solvent and a solution of a nonelectrolyte in that solvent, and it is directly proportional to the molal concentration of the solution
Molal Boiling-Point Constant (Kb)
The boiling point elevation of the solvent in a 1-molal solution of a nonvolatile, nonelectrolyte solute (0.51 C for water)
Boiling-Point elevation
the difference between the boiling points of the pure solvent and a nonelectrolyte solution of that solvent and it is directly proportional to the molal concentration of the solution
Semipermeable Membrane
Allows the passage of some particles while blocking the passage of others
Osmosis
The movement of solvent molecules through a semipermeable membrane from the side of lower solute concentration tot he side of higher solute concentration
Osmotic Pressure
the external pressure that must be applied to stop osmosis