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Arrhenius theory
Acids produce Hydronium Iions, H3O+ in aqueous solutions. Bases produce hydroxide ions, OH- in aqueous soltions by dissociation of ions and reaction with water.
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Bronsted-Lowry
Does not require water as the solvent. Acid is a proton donor. Base is a proton acceptor. Conjugate bases.
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strong acids
- in water, produce almost 100% H3O+
- (equilibrium is far to the right - K is large)
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weak acids
- in water, produce very little H3O+
- (equilibrium is far to the left - K is small)
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strong bases
- in water, produce
- almost 100% OH- (equilibrium is far to the right – K is large)
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weak bases
- in water, produce very little OH-
- (equilibrium is far to the left - K is small)
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amphiprotic
except for H2O, the amphiprotic substance will be negatively charged and contain a H at the beginning of the chemical formula
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position of the equilibrium
- the position of the equilibrium is shifted
- away from the stronger acid, i.e. to the opposite side
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the strength of a weak acid
determined by the acid ionization constant, Ka - the greater its value, the stronger the acid
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equilibrium expression?
H2CO3 + H2O <--> H3O+ + HCO3-
- Keq = [H3O+][HCO3-]
- [H2CO3][H2O]
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