the chemical bond that results from the sharing of valence electrons
molecule
formed when two or more atoms bond covalently
Lewis structures
use electron-dot diagrams to show how electrons are arranged in molecules (H-H)
sigma bond
single covalent bond; occurs when the electron pair is shared in an area centered between the two atoms
pi bond
multiple covalent bond; formed when parallel orbitals overlap to share electrons
bond length
the distance between the two bonding nuclei at the position of maximum attraction; determined by the size of the atoms and how many electron pairs are shared--as the number of shared electron pairs increases, bond length decreases
bond dissociation energy
the amount of energy required to break a specific covalent bond
endothermic reaction
occurs when a greater amount of energy is required to break the existing bonds in the reactants than is released when the new bonds form in the product molecules (cold)
exothermic reaction
occurs when more energy is released forming new bonds than is required to break bonds in the initial reactants (hot)
binary acid
contains hydrogen and one other element
oxyanion
a polyatomic ion that contains oxygen
oxyacid
any acid that contains hydrogen and an oxyanion
structural formula
a molecular model that uses letter symbols and bonds to show relative positions of atoms
resonance
a condition that occurs when more than one valid Lewis structure can be written for a molecule and ion
resonance structures
the two or more correct Lewis structures that represent a single molecule or ion
coordinate covalent bond
forms when one atom donates a pair of electrons to be shared with an atom or ion that needs two electrons to become stable
expanded octet
compounds that have central atoms that contain more than eight valence electrons; occurs with elements in period three or higher
VSEPR model
Valence Shell Electron Pair Repulsion model; based on an arrangement that minimizes the repulsion of shared and unshared pairs of electrons around the central atom; used to determine molecular shape
bond angle
the angle formed by any two terminal atoms and the central atom
hybridization
a process in which atomic orbitals are mixed to form new, identical hybrid orbitals; each hybrid orbital contains one electron that it can share with another atom; carbon does this the most
electron affinity
a measure of the tendency of an atom to accept an electron; increases as the atomic number increases within a period and decreases as the atomic number increases within a group
polar covalent
results from unequal sharing because of a difference in electronegativity
van der Waals forces/intermolecular forces
weak forces of attraction between individual molecules; weaker than the bonds that join atoms in a molecule or ions in an ionic compound
Author
zpetko
ID
7884
Card Set
Chemistry Ch. 9 Vocab
Description
Vocabulary words from Glencoe Chemistry chapter 9, Covalent Bonding