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Atoms
- basic unit of all matter
- made of protons, neutrons and electrons
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Atomic #
number of protons (or # of electrons if atom is neutral)
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Atomic Mass
# of protons plus # of neutrons
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Electron orbits
- 1st inner orbital holds 2 electrons (lowest energy)
- 2nd and 3rd outer orbitals hold 8 electrons each (the farther out, the HIGHER energy)
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Valency
- # of electrons that are required to complete the outermost shell
- ie: carbon, has a valency of 4...so needs 4 electrons to fill the 2nd shell & get 8 total in that shell
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Properties of water.
Hydrogen bonds produces a polar molecule�so can DISSOLVE compounds. It makes up about 70% of organisms by weight. Acidity is based on ionization of water to H+ (acid) and OH- (base), so when equal, pH is neutral.
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Why is water such a good solvent?
Hydrogen bonds produces a polar molecule�so can DISSOLVE compounds.
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Covalent bond
- STRONGEST of bonds. Involves sharing of electrons between atoms. These are difficult to break. They can be polar or non-polar.
- Non-polar involves no charge, atoms with similar electronegativies
- Polar has a slight charge, ie: O-H, with oxygen having the higher electronegativity it is slightly negative, and H is slightly positive.
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ionic bond
- Formed by an atom GAINING or LOSING electrons
- Ie: NaCl, where Na gives up its electron to Cl. So it�s Na+ and Cl-
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hydrogen bond
- WEAKEST of the three bonds. Formed from attraction of positively charged hydrogen (H) atom. This can be with Nitrogen or Oxygen commonly.
- Hydrogen bonds occur in molecules such as water, or in DNA between molecules (C & G and A & T creating double helix)
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Macromolecules
- very large molecules. All macromolecules are polymers and when they join, water is lost, so the reaction is a dehydration synthesis
- divided into 4 classes
- 1. proteins
- 2. polysacchardies (carbs)
- 3. lipids
- 4. nucleic acids
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dehydration synthesis
occurs when water is lost due to polymers joining together to form macromolecules
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hydrolysis reaction
happens when macromolecules breakdown into smaller subunits, and water is added
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Proteins
- Functional parts of the cell
- Function depends on the SHAPE of the protein
- 50% of cell dry weight
- made of AMINO ACIDS (AA's)
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Bonds formed with proteins
- peptide bonds: occur between an amino group (-) and the carboxyl group (+) of AA's.
- the peptide bond formation is a dehydration synthesis reaction
- 2 AA's = dipeptide
- >2 AA's = polypeptide
- 3 AA's = tripeptide
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Polymer/monomer
A protein is a polymer, and an Amino Acid is a monomer
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Functions and/or role of proteins
- enzymes that catalyze reactions
- aid in shaping of certain BACTERIAL structures
- involved in GENE regulation
- nutrient procurement (takes nutrients)
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Structures of proteins
- primary: made of peptide bonds
- secondary: hydrogen bonds
- tertiary: hydrogen bonds plus Ionic bonds b/w side chains
- quaternary: same as tertiary
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Carbohydrates
- contain Carbon, hydrogen and Oxygen
- 1:2:1 ratio
- polysaccharides: large molecules made of carbohydrates
- oligosaccharide: short chain of carbohydrates
- monosaccharide: 1 carbohydrates
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monosaccharides
- classified by number of carbons present in the carbohydrate
- ie: five carbon sugars = pentose (ribose & deoxyribose)
- ie: six carbon sugars = hexose (glucose, fructose, galactose)
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dissacharides
- 2 monosacchardies joining thru dehydration synthesis
- ie: glucose + galactose = lactose
- ie: glucose + fructose = sucrose
- ie: glucose + glucose = maltose
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polysaccharides
- cellulose most abundant, STRUCTURAL component of cell wall formed by many glucose molecules together
- glycogen is carbohydrate STORAGE molecule
- Dextran STORES carbon & energy for bac
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Nucleic Acids
- FXN: Determine specific properties of the cell
- 2 types: RNA and DNA
- subunits are nucleotides
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Nucleotides
- composed of 3 units
- 1. nitrogenous base (C,G,A or T..or U)
- 2. phosphate group
- 3. 5 carbon sugar (deoxyribose..ribose)
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Bonds
- Nucleotides joined by covalent bonds: b/w phosphate of one nucleotide and teh sugar of the other.. 5' to 3' direction
- carbon 5 of phosphate is attached to carbon 3 of sugar
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DNA bonds
- hydrogen bonds connect the two strands to make dsDNA
- A2T, C3G
- PURE As Gold (A & G are purines)
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RNA bonds
- same as DNA, but..
- thymine replaced by uracil
- sugar is ribose vs. deoxyribose
- exists as SINGLE strand
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Lipids
- SMALLEST of the 4 macromolecules
- insoluble in H20
- 2 classes: simple and compound lipids
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Simple lipids
- Contain ONLY C, H & O
- ie: Fats, made of glycerol and Fatty acids
- glycerol has OH groups which allow for binding of 3 fatty acids (triglyeride)
- ie: steroids
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Compound Lipids
- contain fatty acid, glycerol & OTHER ELEMENTS
- ie: phospholipid
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Phospholipid
- Major component in lipid CELL MEMBRANE
- made of phosphate & 2 Fatty acids attached to a glycerol
- phosphate is polar & soluble in water, fatty acids non polar & hydrophobic
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Saturated fats
have all SINGLE bonds in fatty acid chain
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