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Physical and Chemical Properties
- Physical: chemical bonds are not broken can be observed
- Chemical: can only be observed when a substance is changed into another substance
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Intensive and Extensive Properties
- Intensive: independent of the amount of the substance that is present. Ex: density, boiling pt, etc.
- Extensive: depend upon the amount of the substance is present. Ex: mass, volume, energy, etc
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Physical and Chemical Changes
- Physical: changes in matter that do ot change the compostition of a substance Ex: temp, volume, changes in states
- Chemical: result in new substances E: combustion, oxidation, decomposition
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Distillation
Filtration
Chromatography
- D: uses differencs in the boiling points of substances to spearate a homogeneous mixture into its components
- F: substances are separated from liquids and solutions
- C: separates substances on the basis of differences in solubility in a solvent
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SI Units of mass, length, time, temp., & amount of a substance
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Fahrenheit to Celsius
Celsius to Fahrenheit
Celsius to Kelvin
- 9/5(C)+32
- 5/9(F-32)
- C+ 273.15
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Accuracy and Precision
- Accuracy: proximity of a measurement to the true value of a quantity
- Precision: proximity of several measurements to each other
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Protons were discovered by...
Neutrons were discovered by ...
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On a periodic table, rows are called _____ and columns are callled ___.
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Periodic Table:
1A; 2A; 6A; 7A; 8A
- alkali metals
- alkali earth metals
- chalcogens
- halogens
- noble gases
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Name the seven diatomic molecules
- Hydrogen
- Nitrogen
- Oxygen
- Flourine
- Chlorine
- Bromine
- Iodine
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Three different reactions
- Combination
- Decomposition
- Combustion
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Theoretical and Actual Yield
- T: calculate
- A: what actually comes out
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Electrolyte and Nonelectrolyte
- E: dissociates into ions when dissolved in water
- N: dissolves in water but do not dissociates into ions
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Seven strong Acids & formulas...the are also...?
- Hydrochloric Acid: HCl
- Hydrobromic Acid: HBr
- Hydroiodic Acid: HI
- Chloric Acid: HClO2
Perchloric: HClO4 Nitric Acid: HNO3 Sulfuric: H2SO4- ELECTROLYTES
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Strong Electrolytes are..
- strong acids
- strong bases
- soluble ionic salts
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Soluble Ionic Compounds & Insoluble Compounds and important exceptions
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Ionic Equation stuff
all strongelectrolytes, atrog bases, ad soluble ionic salty are siddociated into their ions when determinity the net ionic equation
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Neutralization Reactions
solutions of an acid and a base are combined an the products are asalt an water
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When a strong acid reacts with a strong base, what is the net ionic equation
H and OH produces H2O
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when a carbonate or bicarbonate or sulfite reacts with an acid, what are the products?
salt, carbon dioxide or sulfur dioxide, and water
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Sign conventions for q, w, and delta E.
- q is positive when system gains heat
- q is negative when system loses heat
- w is positive when work done on system
- w is negative when work done by system
- delta E positive when net gain of energy by system
- delta E negative when net loss of energy by system
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Endothermic and Exothermic
- heat absorbed by the system from the surroundings
- heat released by the system into the surroundings
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which are state functions:
internal energy, heat, work
i.e.
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when enthalpy is positive..
when enthalpy is negative..
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Planck's constant, h
6.626 x 10-34 J-s
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Speed of light, c
3.00 x 108
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Rydberg constant, RH
2.18 x 10-18 J
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Quantum numbers:
values of n
values of l
values of ml
values of ms
- n > or = 1
- l are integer ranging for 0 to n-1
- ml are integers ranging from -l to l
ms have only two values: +1/2 & -1/2
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Cations are ____ than their parent atoms.
Anions are ____ than their parent atoms.
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Sizes of Ions increase as....
- you go down a column
- you go from right to left on a period
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isoelectronic series
ions have the same number of electrons
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ionization energy
amount of energy required to remove an electron form the ground state of a gaseous atom or ion
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ionization energy increases as..
- you go up a column
- and left to right across a period
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electron affinity
- opposite of ionization
- energy change accompanying the addition of an electron to a gaseous atom
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in general electron affinity becomes more exothermic as ....
you go from left to right across a row/perid
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metallic character increases as..
you go from left to right across a row/period and down a column
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characteristics of metals
- ductile and malleable
- shiny...luster
- good conductors of electricity
- tend to form cations in aq solutions
- most metal oxides are ionic solids that are basic
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characteristics of nonmetals
- do not have luster; various colors
- solids are usually brittle, some hard some soft
- poor conductors of electricity
- nonmetal oxides are molecular substances that form acidic solutions
- tend to form anion or oxyanions in aq solutions
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three chemical bonds
describe each
- ionic (electrostatic attractions b/w ions)
- covalent (sharing of electrons)
- metalllic (metal atoms bonded to several other atoms)
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lattice energy
energy required to completely separtae a mole of a solid ionic compound into its gaseous ions
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bond dipole
when two atoms share elecrons unequally
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electronegativity
th ability of atoms in a molecule to attract electons to themselves
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electronegativity increases as....
- you go from left to right across a row
- up a column
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sigma and pi bonds
- sigma: cylindrical symmetry ofelectron density about the internuclear axis
- pi: electron density above and below the internuclear axis
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