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What are the Polar-Aprotic Solvents?What reaction is favored in this solvent?
CH3COCH3;DMSO;HMPA;CH3SOCH3. SN2
What is the order of good nucleophiles?
RS->HS->NH2->CN->I->RO->HO->N3->BR->CH3CO2->CL->F->H2O
What is the order of nucleophelicity in P.A.S.?
F>Cl>Br>I
What is the order of nucleophilicity in P.P.S.
I>Br>Cl>F
What is the stability in increasing order of conformational analysis in cyclohexane?
Half-Chair<Boat<Twist<Chair
What are the polar protic solvents? What reaction is favored?
CH3OH;R-OH;H2O;O-H. SN1
What is preferred at high temperatures with strong hindered base and a primary position?
E2
Who is the biggest loser/dork/loner in organic chemistry?
Brian duhhhhhh!!!
Who is the coolest most beautiful girl in the world?
Danielle Freeman
What is favored at low temperatures and primary and secondary positions?
SN2
What type of reactions preferred at lower temperatures and tertiary positions?
SN1
Name the strong bases
NH2-;RO-;HO-;tert-butoxide
What is a sterioisomer that is not a mirror image and is cis/trans?
Diasteriomer
What is a sterioisomer that is also a mirror image?
Enantiomer
What position do larger substituants prefer. axil or equitorial?
Equitorial
What is the order of decreasing stability and increasing energy of eclipised, gauche, and anti?
Anti>Gauche>Eclipsed
What is more polar CHI3 or CHCL3?
CHCL3
What is more polar cis or trans of the same element?
Cis
What does Br2 --->CCl4 do?
adds 2 Br anti addition
Isomers
Different compounds with the same molecular formula. They
DO
have different physical properties!
Constitutional isomers have the same molecular formula, but differ in ___________.
connectivity
In resonance theory
The actual molecule or ion will be better represented by a hybrid structure--an avg or all resonance structures
Compounds that differ only in the arrangement of their atoms in space are called_________.
Stereo Isomers
What is this, a school for _________?
ants
The energy of electrons in a bonding molecular orbital is ____ than the energy in their separate atomic orbitals.
Less
Have you ever wondered if there was more to life, other than being really, really, ridiculously _________?
good looking
sp
3
orbitals have what formation?
tetrahedral
sp
2
orbitals have what formation
triginal planar
_________are steroisomers whose molecules are non superposable mirror images of each other.
Enantiomers
enatiomers have _____ physical properties
identical
________ are stereoisomers whose molecules are not mirror images of each other.
Diastereomers
Enantiomers occur only with compounds whose molecules are _________.
Chiral
This little piggie went_____________________.
wee wee wee all the way home! (hope you guessed this one)
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Author
Anonymous
ID
55393
Card Set
ORgo
Description
Orgo Final
Updated
2010-12-13T01:38:21Z
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