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What are the Polar-Aprotic Solvents?What reaction is favored in this solvent?
CH3COCH3;DMSO;HMPA;CH3SOCH3. SN2
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What is the order of good nucleophiles?
RS->HS->NH2->CN->I->RO->HO->N3->BR->CH3CO2->CL->F->H2O
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What is the order of nucleophelicity in P.A.S.?
F>Cl>Br>I
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What is the order of nucleophilicity in P.P.S.
I>Br>Cl>F
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What is the stability in increasing order of conformational analysis in cyclohexane?
Half-Chair<Boat<Twist<Chair
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What are the polar protic solvents? What reaction is favored?
CH3OH;R-OH;H2O;O-H. SN1
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What is preferred at high temperatures with strong hindered base and a primary position?
E2
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Who is the biggest loser/dork/loner in organic chemistry?
Brian duhhhhhh!!!
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Who is the coolest most beautiful girl in the world?
Danielle Freeman
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What is favored at low temperatures and primary and secondary positions?
SN2
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What type of reactions preferred at lower temperatures and tertiary positions?
SN1
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Name the strong bases
NH2-;RO-;HO-;tert-butoxide
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What is a sterioisomer that is not a mirror image and is cis/trans?
Diasteriomer
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What is a sterioisomer that is also a mirror image?
Enantiomer
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What position do larger substituants prefer. axil or equitorial?
Equitorial
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What is the order of decreasing stability and increasing energy of eclipised, gauche, and anti?
Anti>Gauche>Eclipsed
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What is more polar CHI3 or CHCL3?
CHCL3
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What is more polar cis or trans of the same element?
Cis
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What does Br2 --->CCl4 do?
adds 2 Br anti addition
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Isomers
Different compounds with the same molecular formula. They DO have different physical properties!
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Constitutional isomers have the same molecular formula, but differ in ___________.
connectivity
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The actual molecule or ion will be better represented by a hybrid structure--an avg or all resonance structures
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Compounds that differ only in the arrangement of their atoms in space are called_________.
Stereo Isomers
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What is this, a school for _________?
ants
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The energy of electrons in a bonding molecular orbital is ____ than the energy in their separate atomic orbitals.
Less
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Have you ever wondered if there was more to life, other than being really, really, ridiculously _________?
good looking
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sp3 orbitals have what formation?
tetrahedral
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sp2 orbitals have what formation
triginal planar
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_________are steroisomers whose molecules are non superposable mirror images of each other.
Enantiomers
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enatiomers have _____ physical properties
identical
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________ are stereoisomers whose molecules are not mirror images of each other.
Diastereomers
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Enantiomers occur only with compounds whose molecules are _________.
Chiral
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This little piggie went_____________________.
wee wee wee all the way home! (hope you guessed this one)
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