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Gases, Kinetics, and Chemical Equilibrium
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Mean free path is:
The distance traveled by a gas molecule between collisions.
Four ideal gas characteristics
gas molecules of zero volume
gas molecules exert no forces on other repulsive forces due to collisions
gas molecules make completely elastic collisions
the average kinetic energy of gas molecules is directly proportional to the temperature of the gas
The ideal gas law is:
PV = nRT
R = 0.08206 L atm K
-1
mol
-1
Charle's law says that:
volume
is
proportional
to
temperature
at
constant
pressure
Boyle's law says that:
volume
is
inversely proportional
to
pressure
at
constant
temperature
Avogadro's law states that:
volume
is
proportional
to the
number of moles
at
constant
temperature
and
pressure
Solving for the partial pressure of a particular gas:
χ
a
* P
total
= P
a
Dalton's law of partial pressures states that:
the total pressure is equal to the sum of the partial pressures
P
total
= P
a
+ P
b
+ P
c
+ ... + P
n
Relationship between velocity and mass of two gases
v
1
/ v
2
= √m
2
/ √m
1
Real gases differ from ideal gases because they exhibit these behaviors
V
real
> V
ideal
P
real
< P
ideal
For a new molecule to be formed according to the collision theory 2 requirements must be met:
molecules collide with enough kinetic energy (to overcome activation energy)
molecules collide in the correct orientation
What is the relationship between temperature and rate of reaction
Temperature and rate of reaction is proportional. As the temperature increases so does the rate of the reaction.
Author
xxazncutiexx
ID
43637
Card Set
Gases, Kinetics, and Chemical Equilibrium
Description
Gases, Kinetics, Chemical Equilibrium
Updated
2010-10-27T10:01:38Z
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