Naming Chemical Compounds

  1. How is an ionic compound named?
    • First part: The name of the metal ion is the same as its element name. Use a roman numeral in parenthesis to indicate charge if variable.
    • Space: A space separates the name of the cation from the name of the anion;
    • Second part: The name of the nonmetal ion is obtained by using the first syllable of its element name followed by ide. If polyatomic, use appropriate suffix (ate or ite) and prefix (per or hypo).
    • Subscripts: do not affect the name
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  2. How is a metal ion with a variable charge named?
    A Roman numeral that is equal to the ionic charge is placed in parentheses immediately after the name of the metal.
  3. What is a polyatomic ion?
    A group of covalently bonded nonmetal atoms that has an overall charge. Most are nonmetals such as P, S, C, or N covalently bonded to O atoms.
  4. T or F? Most polyatomic ions are anions
    True. Exception: NH4+
  5. T or F? For the same nonmetal,the per/ate and hypo/ite ions have the same charge
    True
  6. Which ion is written first when naming ionic compounds containing polyatomic ions?
    • Cation is written first: usually a metal
    • Anion is written second: usually a nonmetal
  7. How are polyatomic ions named?
    • ate: suffix for most polyatomic ions
    • per: add prefix if 1 more O atom than -ate
    • ite: suffix if one less O atom than -ate
    • hypo: add prefix if 1 less O atom than -ite
    • Exceptions: hydroxide (OH-) and cyanide (CN-) ions
  8. Name the 4 polyatomic ions for chlorine and oxygen
    • ClO4-: perchlorate
    • ClO3-: chlorate
    • ClO2-: chlorite
    • ClO-: hypochlorite
  9. Why do you need to know if a metal is a representative element or a transition element when naming an ionic compound?
    If it is a transition element, except for zinc, cadmium, or silver, you need to use its ionic charge as a Roman numeral as part of its name. The ionic charge balances the negative charge of the anions.
  10. T or F? In ionic compounds, metals form cations and nonmetals form anions
    • True
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  11. T or F? The transition metals (groups 3-12) have variable charge
    True: except for zinc (Zn2+), cadmium (Cd2+) and silver (Ag+)
  12. T or F? Metals in groups 14 and 15 have variable charge
    True: for example lead, tin, and bismuth
  13. T or F? Halogens (group 17) form four different polyatomic ions with oxygen.
    True: Fluorine, Clorine, Bromine, Iodine
  14. Name 11 metals with variable charge, that is, that form more than one positive ion
    • Bismuth (Bi): (III) and (V)
    • Chromium (Cr): (II) and (III)
    • Cobalt (Co): (II) and (III)
    • Copper (Cu): (I) and (II)
    • Gold (Au): (I) and (III)
    • Iron (Fe): (II) and (III)
    • Lead (Pb): (II) and (IV)
    • Manganese (Mn): (II) and (III)
    • Mercury (Hg): (I)-see note and (II)
    • Nickel (Ni): (II) and (III)
    • Tin (Sn): (II) and (IV)

    Note: Hg(I) ions form an ion pair with a 2+ charge
  15. How is a molecular compound named?
    • First nonmetal: named by its element
    • Second nonmetal: named using the first syllable of its element name, followed by ide.
    • Subscripts: use a prefix to indicate the number of atoms of an element
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  16. Name the prefixes that indicate the element subscripts when naming molecular compounds
    • 1: mono (optional)
    • 2: di
    • 3: tri
    • 4: tetra
    • 5: penta
    • 6: hexa
    • 7: hepta
    • 8: octa
    • 9: nona
    • 10: deca
  17. What is the derivation of the word acid?
    acidus: Latin for "sour" (e.g., vinegar and lemons)
  18. What is an acid/base?
    • Arrhenius: When dissolved in water, acids produce hydrogen ions (H+) and bases dissociate into hydroxide ions (OH-) and cations
    • Brønsted-Lowry: acids can donate a hydrogen ion (H+); bases can accept one (need not contain OH- ions)
    • Litmus paper: red
    • Phenolphthalein: colorless
  19. Pronounce Phenolphthalein
    • Pronounced: fee-nol-thay-lean
    • Phenolphthalein: C20H14O4
    • Shorthand: HIn or phph
  20. T or F? Acids dissolve in water to produce hydrogen ions and anions.
    True: The negative ion may be a nonmetal anion or a polyatomic ion.
  21. T or F? Free hydrogen ions (H+) may exist in water
    False: it bonds to water to form a hydronium ion, H30+
  22. How are bases named?
    • Typical Arrhenius bases are named as hydroxides
    • NaOH: sodium hydroxide (most common Arrhenius base)
    • KOH: potassium hydroxide
    • Ba(OH)2: barium hydroxide
    • Ca(OH)2: Calcium hydroxide
    • Al(OH)3: aluminum hydroxide
  23. How are acids named?
    • Nonmetal anion: hydro is used before the name of the nonmetal anion with its ide ending changed to ic acid
    • Polyatomic anion: ate is changed to ic acid or ite to ous acid
    • Example 1: HCl is hydrochloric acid
    • Example 2: HClO3 is chloric acid, HClO2 is chlorous acid
  24. T or F? The most common form of an oxygen-containing acid has a name that ends with ic acid
    True: The name of its polyatomic anion ends in ate.
  25. What is a conjugate acid-base pair?
    • Molecules or ions related by the loss and gain of one H+
    • Example 1: HF (acid) donates a proton to F- (conjugate base)
    • Example 2: H2O (base) gains a proton from H3O+ (conjugate acid)
  26. T or F? Water can act as an acid or a base
    True: its behavior depends on the other reactant
  27. Define amphoteric (aka amphiprotic)
    Substances that can act as either an acid or a base in water
  28. Name some common acids
    • -ic acids: HF, HCl, HBr, HI, HCN, HNO3, H2SO4 (sulfuric), H2CO3 (carbonic), HC2H3O2 (acetic), H3PO4 (phosporic)
    • -ous acids: HNO2 (nitous), H2SO3 (sulfurous), H3PO3 (phosphorous)
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  29. What is a conjugate acid-base pair?
    • The acid donates a proton and the base accepts it
    • After donating a proton the acid becomes its conjugate base
    • After accepting a proton the base becomes its conjugate base
    • One pair occurs in the each direction
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Author
mikedutch
ID
353739
Card Set
Naming Chemical Compounds
Description
General, Organic, and Biological Chemistry: Structures of Life, 6e by Karen TImberlake
Updated