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Chemistry - Organic Compunds
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Complete Combution
Key term
: excess oxygen
Eg. Ethane + Oxygen -> Carbon Dioxide + Water
Incomplete Combustion
Key Term
: colourless and toxic gas
Eg. Ethan + Oxygen -> Carbon Monoxide + Water
or
Key Term
: Black Soot
Eg. Ethane + Oxygen -> Carbon + Water
Structural Formula
Condensed Structural Formula
shows oder but not bonds
eg. CH
3
CH
2
CH
3
The first four alkanes are ___ at room temperature
The first four alkanes are
gases
at room temperature
Alkanes are insoluble in water so will form _ ______ as they are ___-____
Alkanes are insoluble in water so will form
2 layers
as they are
non-polar
Alkanes boiling points _______ with the length of the carbon chain. As .......
Alkanes boiling point
increase
with the length of the carbon chain as
more energy is needed to separate molecules
.
Alkanes have _____ ____________ forces but their ________ forces are ______ _____________
Alkanes have
covalent intramolecular
forces. But their
intermolecular
forces are
weak intermolecular
Observation: when bromine water is added to a alkane it...
Turns from orange to colourless very slowly under a catalyst of
UV light
Observation: WhenBromine is added to an alkene it...
Rapidly changes from orange to colourless
Functional Group: Alkenes
Double bond on carbon chain
Observation: When MnO
4
-
/H
+
is added to an alkane ...
It remains purple
Observation: When MnO
4
-/H
+
is added to an alkene ...
It turns from purple to colourless
Markovnikovs's Rule
A hydrogen will be added to the carbon of the double which already has the most hydrogens. (Major product)
Hydrogenation Catalyst
Pt at room temp
Ni/150
Hydrogenation Equation
Alkene + Hydrogen --Pt or Ni/150--> Alkane
Halogenation Caltalyst
None
Halogenation Equation (Alkene)
Alkene + Halogen ---> Haloalkane
Hydration Catalyst
dil H
2
SO
4
at 330'C
Hydration Equation (Alkene)
Alkene + Water --> Alcohol
Halogenation Equation (Alkane)
Alkane + Halogen --UV Light--> Haloalkane + H(haloalkane)
Halogen Halide Reaction (Alkene)
Alkane + Hydrogen Halide --> Haloalkane
Oxidation Catalyst
MnO
4
-
/H
+
Oxidation Equation
Alkene + Acidified Pottasium Permanganate --> Diol
Polymermerisation Catalyst
High temp and pressure
Dehydration Catalyst
conc H
2
SO
4
Dehydration Equation
CH
3
CH
2
OH -conc H
2
SO
4
-> CH
2
=CH
2
+ H
2
O
Cracking
Alkane --Fe--> Alkane + Alkene
eg. C
20
H
42
--Fe--> C
10
H
22
+ C
10
H
20
Cracking Catalyst
Fe or Al
2
O
3
Functional Group: Alkyne
Triple bond between Carbons
Functional Group: Alcohols
OH (hydroxyl)
Clasifications alcohols/haloalkanes
The number of carbons the functional group is attached to determines the clasification.
Oxidation Reagent (Primary Alcohol)
MnO
4
/H
+
Purple --> Colourless
Cr
2
O
7
/H
+
Orange --> Green
Oxidation (primary alcohols)
Primary Alcohol + Catalyst --> Carboxylic Acid
Alcohols have a ______ melting point than hydrocarbons
higher
Functional Group: Carboxlic Acids
COOH
Carboxylic acids have _____ melting points than alcohols
higher
Carboxylic acids turns _____ litmus paper _____.
Carboxylic acids turn blue litmus paper red.
Carboxylic acids do/do not conduct electricity due to .....
Carboxylic acids do conduct electricity die to free moving ions.
Carboxylic Acids + Metal --> _______ + ________
Carboxylic Acids + Metal --> Metal Salt + Hydrogen
Metal salts have a sufix of ______
Metal salts have a sufix of
anoate
Acid + Base --> _____ + ______
Acid + Base --> metal salt + water
Acid + Carbonate --> _______ + _______ + ________
Acid + Carbonate --> metal salt + water + carbon dioxide
Functional Group: Esters
COO
Naming Esters
C=O side - anoate
O side - thyl
Name :
Methyl Ethanoate
Name:
propyl methanoate
Name:
ethyl propanoate
Name:
butyl propanoate
Carboxylic Acid + Alcohol --H
2
SO
4
--> ____ + _____
Carboxylic Acid + Alcohol --H2SO4--> ester + water
Catalyst: Esterfication
conc H
2
SO
4
Author
kristenanna
ID
34425
Card Set
Chemistry - Organic Compunds
Description
Organic Chem
Updated
2010-09-13T09:22:26Z
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