once gypsum is heated it loses 1.5 of its 2 g mol of H2O and is converted to
calcium sulfate hemihydrate
True/False: When water is added to calcium sulfate hemihydrate the reverse reaction happens and calcium sulfate dihydrate is formed
TRUE
the process in which gypsum is heated and part of the water of crystallization is driven of
calcination
2CaSO4 . 2H2O with open kettle heating creates
Model plaster (type 2)
2CaSO4 . 2H2O with high-pressure steam creates
stone (type 3)
2CaSO4 . 2H2O with Boil and CaCl2 creates
Type 4 and Type 5 high-strength stone
T/F: excess amount of measured water above the theoretically correct amount required for hydration is always necessary
True
amount of gauging water from most to least
plaster> dense particles of stone> high-strength stone
water to powder ratio for:
plaster:
stone:
improved stone:
plaster: 45-50 ml/ 100 g (0.45-0.5)
stone: 28-30 ml/100 g (0.28-0.3)
improved stone: 19-24 ml/ 100 g (0.19-0.24)
the working time is the length of time from the start of the mix until he setting mass reaches a
semi hard stage
the length of time from the start of the mix until the setting mass becomes rigid and can be separated from the impressions
final setting time
Surface penetration test using glimmer needles
initial setting time when:
final setting time when:
the product can support the weight of a 1/4 lb needle
the product can support the weight of a 1 lb needle
In clinical setting what can be used to determine the working time
average working time?
loss of surface gloss
5-7 mins
what can be used to determine relative rigidity and hardness that could be used to indicate final set
average, subjective setting time for final set
failure of penetration by a finger nail or dull knife
30-45 mins
4 ways to increase setting time (a slower-setting product)
decreased mixing
higher water/powder ratio (creates a thinner mix)
addition of retarders (commonly: borax)
lower temperature of water (cold)
4 ways to decrease setting time (a faster-setting product)
increased mixing (the longer the mixing time the shorter the setting time)
lower water/powder ratio (creates a thicker mixture
additional of certain chemicals called accelerators (commonly: potassium sulfate)
the first indication of moisture contamination is ___ ___ of the product and if the contamination continues, ____ ____ occurs
faster setting
slower setting
expanding percentages of
plaster:
stone:
high strength stone:
plaster: 0.2% to 0.3% (the most)
stone: 0.08% to 0.10%
high strength stone: 0.05% to 0.07% (the least)
2 things increase setting expansion
thicker mix
increases spatulation
2 things decrease setting expansion
thinner mix
decreased spatulation
increase in setting expansion that occurs when gypsum materials are immersed in or come in contact with water during the setting process
hygroscopic expansion
hygroscopic expansion is ___ as great as the normal setting expansion
twice as great
strength of gypsum product is usually measured in terms of ____ or _____ strength
crushing; compressive
the strength that is measured when the sample contains some or all of the water in excess of the theoretical amount required for hydration; typical condition after setting; material feels well for several hours
wet strength
the strength that is measured when the excess water is not present in the sample
dry strength
the dry strength may be ___ or ___ times the wet strength
2 or 3
T/F: cast must sit in a dry environment overnight to approach dry weight values
True
thicker mixes will ___ strength whereas thinner mixes will ____ strength
increase;decrease
related to compressive strength but reaches it maximum value more rapidly because the surface is the first to dry
surface hardness
when does the greatest surface hardness occur?
when the product reaches its dry strength
if gypsum must be soaked in water for a lab procedure, the water should be saturated with ____ to prevent surface erosion
gypsum
*use a saturated solution of calcium sulfate
1 g of water roughly equals
1 ml
mixing to get a smooth, homogenous mix should be obtained in how much time?
1 minute
*whipping motion should be avoided
provides a gypsum mix free of air bubbles and is homogenous in consistency; used when elimination of voids and surface bubbles is critical