What is the relationship between ionisation energy and Group 2 elements?
As you go down group 2, ionisation energy decreases.
Why does Ionisation energy decrease as you go down group 2? (2 marks)
Electron on the outer shell are further away from the nucleus so the effect of the strong nuclear force is reduced.
More shielding due to extra inner shells as you move down a group.
What are the products of group 2 elements with water and what the general equation? ( 3 marks)
M(S) + 2H2O (l)→ M(OH)2 (aq) + H2 (g)
Hydrogen
Metal hydroxide
What is the trend of re-activity of group two elements with water and why are they like this? Which group 2 metal doesn't react with water?(3 marks)
Reactivity increases as you go down the group.
This is because the ionisation energies decrease as you go down the group
Berylium
Why doesn't Beryllium react with water?
Because of thick oxide layer on the surface of the metal.
What is the product of group 2 elements with oxygen and what is the general equation for this?
Metal oxides
2M(s) + O2 (g) → 2MO(S)
What causes coloured flame in flame test?
Electrons emitting a photon when returns to it ground state
What a more accurate device to measure a flame test and how does it work and what is it used for? (3 marks)
A flame photometer
Measure the wavelength of the emitted light as it corresponds to a colour
Used to find the level of Na+ and K+ ions
What is the trend of reactivity of group 2 metals with oxygen?
As you go down the group reactivity increases.
What is the product of group 2 elements with chlorine gas and what the general equation for this? (2 marks)
Metal chlorides
M(S) + Cl2(g) → MCl2(s)
What is the trend of reactivity of group 2 metals with chlorine?
As you go down the group reactivity increases.
What is the product of group 2 oxides and water ;what the general equation; what is the implication of the reaction and why as well as what group 2 oxide is an exception and what the trend of solubility of metal oxide and why? (2 marks)
Metal hydroxide
MO(S) + H2O(l) → M(OH)2(aq)A strong alkaline solution is produced due to the strong OH- ions
Magnesium oxide - reacts slowly
Solubility increases as you go down the group
because the hydroxides get more soluble
What is the product of group 2 oxides and hydrochloric acid and what is the general equation for this? (2 marks)
Chloride salt and water
MO(s)+2HCl(aq) → MCl2(aq)+H2O(l)
What is the product of group 2 oxides and dilute nitric acid and what is the general equation for this? (2 marks)
nitrate salt and water
MO(s)+2HNO3(aq)→M(NO3)2(aq)+H2O(l)
What are oxides and hydroxides and what implication does this have? (2 marks)
They are bases so can neutralise dilute acids.
What is the product of group 2 hydroxides and dilute hydrochloric acid and what is the general equation for this?(2 marks)
group 2 metal chloride and water
M(OH)2(S) + 2HCl (aq) → MCl2(aq) +2H2O(l)
What is the product of group 2 hydroxides and dilute nitric acid and what is the general equation for this?(2 marks)
group 2 metal nitrate and water
M(OH)2(S)+2HNO3(aq) → M(NO3)2(aq)+2H2O(l)
What is the general equation of group 2 metals and sulphate;what is the trend for group 2 sulphate and which group sulphate is insoluble?(2 marks)
M+ H2SO4 → MSO4 + H2
Group 2 sulphate solubility increases as you go up the group.
Barium Sulphate
What the relationship between group 2 elements and carbon cations? ( 2 marks)
Compounds of group 2 elements that contain singly charged negative ions (e.g OH-) increase solubility down the group.
Compounds of group 2 elements that contain doubly charged negative ions (e.g SO42-) increase solubility up the group.