What are the two sources of waste streams in conventional treatment?
Sedimentation sludge filtration waste washwater
Of these two which is generally of the greater quantity?
Sedimentation Sludge
Filtration wast wahswater
Wast wash water
Which is generally of the greater solids density?
Filtration wash water or sedimentation sludge?
Sedimentation sludge
What is usually the first facility used to process waste wash water?
Wash water recovery Basins
What two functions are performed in a typical washwater recovery basin?
Flow Equalization sedimentation
What process uses gravity to separate suspended solids from water?
Sedimentation
Stores high waste stream flows before slowly returning them to the main plant flow stream?
Flow Equalization
What is the maximum rate of return permitted for recycled waste streams into the main flow stream?
10 %
What is the maximum turbidity allowed foe recycled waste streams?
2 TUs.....Turbidity Units
What process is typically used as the final dewatering step in sludge processing?
Sludge drying beds
What type of chemical will form DBPs during normal treatment operations?
Disinfectant
Which of the following will cause the sludge produced from the Sedimentation process to increase in percent solids?
Decreasing the frequency of sludge removal
Where is the most likely first destination for waste washwater leaving the Filtration process?
Washwater recovery basins
The underflow from Washwater Recovery is normally piped to the
Sludge thickening process
The maximum percentage of the total plant flow that can be from recycled waste streams is
10 %
Which of the following processes produce a waste stream?
Sedimentation
The waste stream generated by the Sedimentation process is known as
Sludge
The relatively clear water that forms the effluent stream from a Sedimentation process is called the
Decant
Washwater recovery basins serve two key functions. These are
Flow equalization and solds removal
he approximate percentage of solids in Sedimentation process sludge is
1 %
Which of the following processes produce waste streams?
Filtration
Moderate or High TOC levels in raw water may require which of the following treatment processes?
Enhanced coagulation
How many carbon atoms are present in the molecules of HAAs?
2
Which of the following disinfectants will generally produce the lowest overall levels of currently regulated DBPs?
Chloramines
Which of the following will react with chemical disinfectants during drinking water disinfection?
Non-pathogenic microorganism
Natural organic matter
Algae
Pathogens
Which of the following processes could be effective in the reduction of THM precursors?
Aeration
Advanced membrane processes
Activated carbon filtration
What will be the likely impact of elevated raw water Bromide levels on DBP formation?
Higher levels of TTHMs, HAAs, and Bromate
DBPs sometimes found as trace impurities in commercially available sodium hypochlorite solutions include
Chlorate
Chlorite
Bromat
Which of the following would be considered Natural organic matter?
Algae
Debris from plants and animals
from the watershed
Live microorganisms
Dead pathogens
What is the MCL for TTHMs?
80 ug/L
The overall level of precursor material for THM production is measured in the laboratory as
Total organic carbon
How many carbon atoms are present in the molecules of HAAs?
2
The main public health risk attributed to TTHMs and HAAs is
Carcinogenicity
Which of the following would be considered as a moderate level of TOC?
3 mg/L
disinfectants is likely to form the highest level of THMs?
Free chlorine
Approximately what percentage of the water captured in the waste streams of Conventional Treatment plants is recovered and recycled through the main treatment plant?
99 %
The approximate percentage of solids in Sedimentation process sludge is
1 %
The waste stream generated by the Sedimentation process is known as
Sludge
Which of the following is likely to cause a deterioration in the performance of the Filtration process?
Rat-holing
Hydraulic surging
Flow equalization
Supplemental scoural
Hydraulic surging
Chlorine is applied at a dosage rate of 2.5 mg/L. After a reaction time of over 4 hours in the clearwells, the chlorine residual is 1.5 mg/L. What is the chlorine demand?
1.0 mg/L
A 20 MGD conventional plant must achieve a CT of 60 mg/L*minutes for disinfection. If its disinfection process has a t10/T ratio of 0.80 and a maximum theoretical detention time of 60 minutes, at what minimum disinfectant residual must they operate?
1.25 mg/L
A clearwell is 120 feet in diameter and has a water level of 24 feet. What is the theoretical detention time in this tank if the t10 is 100 minutes, and the t10/T ratio is 0.65?
154 minutes
When ozone gas is processed through an ozone destruction unit, the outlet gas will contain a high concentration of
Oxygen
Ozone is produced by applying electrical energy to a gas stream that contains
Oxygen
Disinfectants that are also capable of improving coagulation, oxidizing iron and manganese, and producing other treatment benefits include
D. All of the above
the following shows the correct ranking of disinfectant effectiveness (from best to poorest)?
The drinking water disinfectant that is the triatomic form of oxygen is
Ozone
When used alone, sodium hypochlorite and calcium hypochlorite will produce which of the following disinfectants in drinking water
Free chlorine
Disadvantages to the use of chlorine dioxide include
increased levels of the DBP chloriteFew current users in the USAVery little persistence of a disinfectant residualOccasional customer complaints of water odor
Chlorine symbol
Cl2
Hypochlorous Acid
HOCL or HCLO
Hypochlorite ion
OCL-
MonoChloramine
NH2Cl
NCl3
Trichloramine
Break point Curve
The y axis is total chloramine residual +chlorine residual combined
1mg/l sodium Thiosulfate neutralizes
1mg/L Cl2
Combined chlorine reacts as well
no residual after reaction
hydrogen sulfide
sym and where found
H2S
found in deep lakes and wells
Nitrite sym
NO2-
Nitrate is NO3-
What chemical is added to water quality samples for dechlorination
Sodium thosulfate
What common metals found in many ground water sources will react with free chlorine?
Iron and Manganese
What odorous gas found in many ground water sources will react quickly with free chlorine?
Hydrogen sulfide
What chemicals is combined with free chlorine to form chloramines
Amonia
What are the three chloramine molecules
Monnochloramine
dichloramine
trichloramine
what is the most desirable chloramine form in drinking water?
Monochloramine
In what form is the total chlorine residual before the final part of the breakpoint curve?
Combined
Free chlorine
What will be the result of adding additional free chlorine to already-formed chloramines?
Chloramine destruction
What are the nitrogen-containing products of chloramine destruction?
Nitrogen gas and Nitrate
Forms of chlorine demand
inorganics; Iron,Manganese,Sulfide
ammonia
chloramines
What is the term for the low spot on the chlorine breakpoint curve where no additional chlorine demand exists?
Breakpoint
which of the three forms of chloramines is the most odorous and the most dominant near the breakpoint?
Trichloramine
In what form is the total chlorine residual to the right of the breakpoint?
Combined Free
what is the term for changing free ammonia into into nitrate?
Nitrifaction
If there is no residual is detected what can be done to satisfy requirments
HPc test Hetrotrophic plate count <500 cfu
SWTR Disinfectants
Free chlorine
chloramines
chlorine dioxide
Ozone
Which form of chlorine residual provides the greatest level of disinfection?
Combined
Free
Free
Which form of chlorine residual yields the highest level of THMs/HAAs?
combined of free?
Free
What is the MRDL for chloramies?
4 mg/L
What is the ideal ratio of chlorine to ammonia
5:1
Converting water with a free chlorine residual to chloraminated water would require the addition of
Ammonia
What is the percentage of ammonia present in Anhydrous ammonia?
100
Which of the following will be formed when adding free chlorine to monochloramines?
Dichloramines
The most effective way to stop nitrification in a distribution system is
Breakpoint chlorination
What is the optimum ratio of chlorine to ammonia-nitrogen for the production of chloramines in a water distribution system?
5:1
In Water Quality, what does MRDL stand for?
None of the above
A total chlorine residual measurement has been made. How many points on the chlorine breakpoint curve might have this same level of total chlorine residual?
3
Which of the following is a form of free chlorine demand?
a. Iron
b. Chloramines
c. Ammoniad. Hydrogen Sulfide
e. All of the above
All of the above
Which of the following is a metal commonly found in groundwater that exhibits a significant chlorine demand?
Calcium
Nickel
Manganese
Sodium
Potassium
Manganese
In addition to the growth of AOBs and NOBs in a water supply that is experiencing nitrification, what else is likely to occur?
Growth of other heterotrophic bacteria
If sufficient free chlorine is added to exceed the chlorine demand of a water source, what form of chlorine residual will be present?
free
hat is the initial chemical that serves as the food supply for microorganisms involved in nitrification?
Ammonia
What will be the chlorine to ammonia ratio when a chloraminated water is blended with a water with a free chlorine residual?
Cannot be determined without further information
Which of the following is an intended purpose of secondary disinfection?
Limiting the growth of microorganisms in the distribution system
When operating a distribution system with chloramines, the ideal ratio of free chlorine to free ammonia is
5:1
The disinfectant that produces the most persistent residual is
Chloramines
What is the MRDL for Chloramines?
4 mg/L
One of the main reasons that a distribution system is required to have a detectable residual disinfectant is to
Protect the water supply from contamination
What is the Primary MCL for Floride?
4mg/l
Risk of excess floride?
bone dissease
What environmental factor is the basis for Floride secondary MCL of 2mg/l
The Average annual Maximum daily air temp
Sodium floride name and %
NaF 45..25%
97%-98% purity
Sodium Florosilicate
Na2SiF6
60.75% Fluoride
solid chemical
least expensive
Saturation lvl varies with temp
Fluorosilicic Acid Chracteristics
H2SiF6
comes dissolved in water
EXTREMELY corrosive Low pH Liquid
79.2%
20-30% because water is the major impurity
What chem are used to add fluoride to drinking water?
Fluorosilicic Acid
Sodium Fluoride
Sodium fluorocilicate
What chem has the highest % Fluoride
Fluorocilic Acid 79.2
How cant excess fluoride be removed?
Advanced treatment like ion exchange or membrane filtration
Density =?
D= weight / Volume
The main impurity found in fluorosilicic acid is
Water
What concern is the basis for the secondary MCL for fluoride?
Dental fluorosis
Which of the following chemicals can be added to drinking water using a saturator?
To determine the proper amount of fluoride to be added to drinking water, we must consider the
Percent fluoride of the chemical
Average annual daily air temperature
Amount of water being treated
Natural level of fluoride
In which particle size category would we place fluoride?
Dissolved
Which of the following elements is most likely to exist in water as an anion?
Sodium
Calcium
Fluorine
Carbon
Fluorine
considered in the establishment of an optimum fluoride level for drinking water?
Average annual daily air temperature
What is the most common means to feed a liquid chemical solution into drinking water supplies?
Positive displacement pumps
What is the most common and cost effective means to reduce natural fluoride levels in drinking water?
Blending with lower fluoride sources
A gravimetric chemical feeder determines the amount of chemical being applied by measuring its
Weight
Which of the following chemicals has the highest percentage of fluoride?
Fluorosilicic acid
Fluoridation chemicals have a known percent fluoride and a specified percent
Purity
The purpose of fluoride addition to drinking water is to improve the
Dental health of children
lending is being used to control arsenic levels. The first source has a flow rate of 1.0 MGD and an arsenic level of 15 ppb. The second source has a flow rte of 1.2 MGD and an arsenic level of 6 ppb. What is the blended arsenic level in ppb?
10
A______is the substance in greatest abundance in a solution.
A________solute is any other substance dissolved withing the _______
Solvent
Solute
Physical removal of particles from materials it contacts
V.S
Chemical removal of particles from materials
Erosion
Corrosion
What is Saturation
The maximum concentration of a solute that can be dissolved within a solution.
Saturation levels depend on
Identity of the solutes
Temperature
pH
Many other factors
Corrosion =
Loss of mass
Deposition
The migration of particles within the water to the wall of the container also known as
Scale formation
Gain of mass
The treatment process used to control corrosion and /or deposition
Stabilization
Galvanic corrosion is caused by
Dissimilar metals that are electrically connected
combating Galvanic corrosion
Interrupt the circuit
Protective coatings
Insulating Flange sets
What effect will increasing water temperature have on corrosion?
increase
Which form of corrosion is more likely due to corrosive water?
Uniform corrosion or Localized corrosion
Uniform corrosion
What is the most common means of estimating the corrosion/deposition tendency of water?
Langlier index
What is the most common means of directly measuring the corrosion/deposition tendency of water?
Coupon Testing
The langlier index for a water sample is calculated to be +.35 will this water tend to be corroding or depositing
positive index Depositing
The addition of acides will _____alkalinity
while
Addition of basses will _______alkalinity
Decrease
increase
Raising the pH will cause _______ (mostly calcium carbonate) to leave the water and coat the container.
Precipitates
_________are used for corrosion control
Phosphate compounds
What is the term for a chemical that ties up other chemicals in the water preventing them from paticipating in reactions including corrosion
Sequestering or chelating agent
Why are Fe/Mn problems more common in ground water?
low Dissolved Oxygen
What zone in a deep lake is most likely to have dissolved iron and manganese?
Hypolimnion
Iron and Manganese secondary standards
Iron-.3 mg/l
Manganese - .05 mg/l
What is the most common means of converting Fe/Mn from dissolved particles into suspended ones?
Oxidation
What is the most common means of removing suspended Fe/Mn particles?
Filtration
What is a common filter medium for Fe/Mn removal?
Manganese Greensand
An insulated flange set is a mechanical device intended to prevent
Galvanic corrosion
Insoluble precipitates of Iron and Manganese can be removed from water by
Conventional filtration
Particles of manganese in drinking water will cause turbidity if they are
Suspended
Corrosion that is caused by electrochemistry between two different metals is known as
Galvanic corrosion
The process by which particles of matter are physically removed by water is known as
Erosion
Raising the pH of drinking water is most likely to cause
Precipitation
A substance dissolved within a homogeneous solution of drinking water is known as a
Parameter
Constituent
Solute
Contaminant
All of the above
hat will be the result of adding free chlorine to water that contains dissolved iron and manganese?
The formation of insoluble precipitates
The most common means of assessing the stability of water is the
Langlier Index
Common acids used in water treatment include
Carbon dioxide
Water that has no tendency to corrode or to deposit is
Anionic
Cationic
Hard
Soft
None of the above
None of the above
The saturation level of a solute in a homogeneous mixture is dependent upon
The identity of the solvent
The identity of the solute
Temperature
pH
Particles of iron in drinking water will be dissolved in size if the water is
Anaerobic
It has been determined that a drinking water supply is slightly corrosive. Which of the following chemicals is most likely to be used to resolve this situation?
Chlorine dioxide
Carbon dioxide
Sulfuric acid
Caustic soda
Ferric chloride
Caustic soda
The dominant substance in a homogeneous mixture is called a
Solvent
What is the term for multivalent cations in the water
Hardness
Are the particles that cause hardness in water
suspended colloidal or dissolved
Dissolved
Types of hardness
Carbonate : Temporary
Non-carbonate: Permanent
Carbonate Hardness is
Calcium and magnesium in combinations with two of the alkalinity anions
Carbonat and Bicorbonate
Why is Carbonate hardness known as temporary hardness
it leaves the water upon heating
A 25 MGD treatment plant using lime/soda ash softening reduces the 280 mg/L total hardness to 40 mg/L total hardness. How many pounds of hardness are removed each day at this facility?
50,040
The process that is most commonly employed to return lime softened water to a near-neutral pH is known as
Recarbonation
In drinking water quality, multivalent cations are responsible for
Hardness
An alternative unit of hardness measurement to milligrams per liter is
Grains per gallon
A natural resin often used in ion exchange softening is
Zeolite
In general, about how much total hardness is removed during conventional treatment?
None
When added to water, which of the following substances would raise the pH?
Lime
Which of the following is a concern posed by hardness in drinking water?
Deposits of hardness are difficult to remove
Formation of films on dishes and porcelain fixtures
Higher consumption of soap for normal cleaning
Formation of scale inside pipes
All of the above
All of the above
How will the surface charge on a resin compare to the surface charge on ions to be removed from the water?
They will be opposites
The conversion of a dissolved particle into a suspended particle is known as
Precipitation
The metallic ions that contribute hardness to the water would fall into which of the following particle size categories?
Dissolved
In contrast with conventional treatment, the amount of sludge generated by a lime softening plant is
Significantly greater
Which of the following is the smallest particle that exhibits all the properties and characteristics of a compound?
Molecule
The high pH and corrosiveness of water treated by lime softening are often alleviated by
Split stream treatment
In which particle size range would ions be classified?
Dissolved
Compared to the number of cationic charges in a water sample, how many anionic charges must be present?
Significantly fewer
Ozone injection through diffusers is an example of which form of aeration?
Gas into water
Packed tower aeration is an example of which form of aeration?
Water into air
What feature of membranes determines the size of particles that will be removed?
Pore size
The name for water entering a membrane process that does not become product water
Reject
Term for the water that becomes product in a membrane treatment process
Permeate
Membrane process that does not require differential water pressure?
Electrodialysis or Electrodialysis Reversal
Membrane process produces water that is similar in quality to that of a conventional treatment plant?
Microfiltration
Name the type of membrane material most commonly used in micro filtration and ultrafiltation
Hollow fiber
Membrane process that is capable of removing all dissolved salts from sea water
Reverse osmosis
Which of the membrane processes produces the largest amount of waste?
Reverse Osmosis
Approx operating pressure of a reverse osmosis process?
300-1200psi
Membrane process that operates at lowest transmembrane perssure
Microfiltration
A mixture of suspended particles in water is known as a
Slurry
What laboratory analysis is used to detect both natural and synthetic organic matter in the laboratory
TOC
the following substances will exhibit an earthy/musty odor in water?
Geosmin
In drinking water treatment, electrodialysis is an example of
Membrane treatment
Humic and fulvic acids are components of
NOM
Which of the following processes will use hollow fiber membranes?
Ultrafiltration
A common means of transferring ozone gas into water is the
Fine bubble diffuser
When two GAC filters are operated in series, the second filter is known as the
Lag unit
In activated carbon filtration, the measurement of detention time in the process is called the