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Shells33
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What are the four forms of matter?
gas, liquid, solid, plasma
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What are the characteristics of a gas?
it possesses neither shape nor volume, expands indefinitely
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What are the characteristics of a liquid?
they possess volume and assume the shape of their container
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What are the characteristics of a solid?
They possess volume and shape. They cannot be compressed.
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What is a plasma?
mixture of ionized gas and free-floating electrons
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What is a substances physical properties dependent upon? What is this dictated by?
- molecular activity
- dictated by heat and pressure
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What determines an element's identity?
its atoms
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What is an element?
a pure substance that cannot be broken down into simpler substance by chemical reactions
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What are the 4 points of Dalton's Atomic Theory?
- 1) all matter is made up of tiny particles called atoms
- 2) all atoms of the same element are identical
- 3) atoms of one element are different from another element
- 4) atoms combine to form molecules
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What is a compound?
a pure substance of 2 or more elements in a FIXED PROPORTION by weight
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What is a mixture?
a combination of elements and compounds (ex: room air)
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What is a molecule?
a tightly chemically bound group of atoms
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What is a chemical bond? What are the two types?
- powerful attraction that holds atoms together
- 1) ionic
- 2) covalent
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What happens as elements in a row move to the right?
atomic weight increases
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What characterizes a family of elements?
- they are in the same column
- they share chemical and physical properties
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Where are the protons and neutrons located?
within the nucleus
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What is the atomic number?
number of protons in the nucleus
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What is the atomic mass?
the weight of the protons and neutrons in the nucleus
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How many electrons typically are in the 1st, 2nd, and 3rd orbits?
2, 8, 8
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When an atom has 8 electrons in its outer orbit it is said to be _____
inert
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What are the 4 elements that are the basis for organic chemistry?
carbon, oxygen, hydrogen, nitrogen
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Which iron is a component of hemoglobin?
Ferrous (Fe +2)
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What is an ion? what are the two types?
- a particle with an unequal number of protons and electrons
- cation (+)
- anion (-)
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What is an ionic bond? is it weak or strong?
the attraction between positive and negative ions. strongest of the electrostatic bonds.
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Ionic bonds include a ____ & _______
metal and non-metal
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How does the charge relate to the strength of bond in ionic bonding?
the greater the charge, the greater the attraction
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What are the 3 concepts of intermolecular forces?
- 1) dipole-dipole
- 2) hydrogen bonding
- 3) london forces
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What is a dipole-dipole attraction?
the attraction between the oppositely charged ions of polar molecules
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What is an ion-dipole bond?
The bond between an ion and a polar molecule
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What is a hydrogen bond?
a special type of ion dipole bond that occurs when hydrogen is bound to N, O, or F
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What is a London force?
An instantaneous pole that is created whenever electrons in a molecule are unevenly distributed.
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What is a covalent bond?
results from SHARING one or more pairs of electrons
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What is the foundational bond of organic chemistry?
the covalent bond
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What is the structure of methane?
CH4
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What is the structure of methyl?
CH3
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What is a radical?
Any group of atoms that have bonded together to act like an individual atom in chemical reactions
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How many covalent bonds can be formed with carbon
4
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How many covalent bonds can be formed with nitrogen
3 or 4
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How many covalent bonds can be formed with oxygen
2
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How many covalent bonds can be formed with hydrogen
1
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How many covalent bonds can be formed with sulfur
2, 4, or 6
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How many covalent bonds can be formed with chlorine
1
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How many covalent bonds can be formed with Fluorine
1
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How many covalent bonds can be formed with Bromine
1
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How many covalent bonds can be formed with Iodine
1
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What is the structure of ethane?
2 carbons, 6 hydrogens (all single bonds)
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How many carbons are in propane?
3
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how many carbons are in butane?
4
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how many carbons are in pentane?
5
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How many carbons are in Hexane?
6
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How many carbons are in heptane?
7
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How many carbons are in octane?
8
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How many carbons are in nonane?
9
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How many carbons are in decane?
10
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What is an alkene?
includes a double bond
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What is alkyne?
includes a triple bond
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What is an isomer?
compounds that have identical molecular formulas but several alternate structures
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What about carbon facilitates isomers?
it has the unique ability to rotate its bonds around its central axis
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What are the two types of isomers? describe.
- 1) Structural - differ in physical and chemical properties, same components, just arranged differently
- 2) Stereoisomer - identical formulas but differ in their spatial arrangement. (2 types: optical and geometric)
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What is an optical isomer?
- when carbons atoms differ from on another in such a way as to polarize the light
- - to the right = dextroisomer
- - to the left = levoisomer
- - mirror images
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How do you get a racemic mixture?
combine dextro and levo isomers so that no bending of light occurs
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What is a geometric isomer? What are the two types?
- when a double bonded carbon prevents axial rotation so the R's move
- - cis isomer (R's on same side)
- - trans isomer (R's on opposite sides)
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What is a functional group?
a set of atoms bound together in a specific way - responsible for the chemical and physical properties of a compound
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What are the characteristics of a halogen compound?
- - functiontional group is a halogen (F, Cl, Br, I)
- - generic formula is R-X
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What are the characteristics of an ether?
- - two radical groups joined by an atom of oxygen
- - oxygen is the functional group
- - generic formula: R-O-R
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What are the characteristics of an ester?
- - alcohol + acid
- - generic formula: R-COO-R
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What are the characteristics of an amide?
- - related to carboxylic acid
- - generic formula: -CONH2
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What are the characteristics of an amine?
- - functional group is the nitrogen atom
- - generic formula: R-NH2
- - can be divided into primary, secondary, tertiary depending on how many of the hydrogen atoms are replaced by a radical
- - derivative of ammonia (NH3)
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What are the three major categories of hormones?
- - proteins or peptides
- - amines or amino acids
- - steroids
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Epinephrine, Norepinephrine, Dopamine, Phenylephrine, dobutaine are all examples of what?
sympathomimetic amines
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What are the general characteristics of an aromatic compound?
- 6 carbon ring with 3 double bonds
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What is a hydroxyl group?
-OH
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What is a methyl group?
CH3
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What is an amine group?
NH2
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What is an isopropyl group?
HC - CH3 - CH3
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What is the difference between NE and E?
methylation of the terminal amine
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