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Chemistry Week 3
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Stoichiometry
Requires a balanced equation
Use coefficients to balance
Limiting Reagent
Is it the cheese or the bread that limits the sandwiches?
Has to do with population size (moles) NOT grams or weight
Grams to Volume
Molar
M=
moles
Liter
Concentration
What is printed on the bottled
Number of moles present in a certain volume of solution
Concentration x Volume= Moles
Dilution Equation
(C
stock
)(V
stock
)= (C
want
)(Volume
want
)
Equations for Concentration
CxV=Moles
MxV=Moles
Moles
xL= Moles
Potential Energy
PE
PE=Mgh
Convert to joules
Kinetic Energy
KE
KE=1/2MV
2
Convert to Joules
M
mass
g
acceleration due to gravity
h
height of object
V
velocity
Specific Heat
C
measure of how strongly molecules or atoms are bound
C=
Joules
(Kg)C
o
Large amount of heat to make temperatures rise 1
o
= strong bond
Reverse is true
c
specific heat
Q
Joules
/\
T=
T
final
-T
starting
Specific Heat of Water
C
water
=4186
J
/(Kg)C
o
Alitropes
Atoms in different configurations/ chemical structure
Isimers
Molecules in different configurations
Balancing (Stoichiometric) Coefficient
Numerical multiplier of all the atoms in th formula that follows it
Molar Mass
M=g/mol
Molar Mass Compounds
Sum of mass of atoms in formula
Chemical Equation
Statement in formulas that express the identities and quantities of the substances involved in a chemical or physical change.
Stoichiometrically Equivalent
A definite amount of one substance is formed from, produces or reacts with a definite amount of the other.
Actual Yield
Amount of product that are actually obtained.
Percent Yield
Actual Yield
X 100%
Theortical Yield
Electrolyte
Substance that conducts a current when dissolved in water
AcidBase Reaction
When an acid reacts with a base
Neutralization reaction
Acid
Produces H
+
ions when disolved in water.
Base
Produces OH
-
ions when disolved in water
Titration
One solution of known concentration is used to determine the concentration of another solution through monitored reaction.
Equivalance Point
All moles of the H
+
ions (acids) react with same number of OH
-
(base) ions.
End Point
(
When titration occures and when a tiny excess of OH
-
(base) changes to its color
Enthalpy (H)
Thermodynamic variable
Exothermic
Heat-out.
Releases Heat
Decreased
(-)
Endothermic
Heat-in
Absorbs Heat
Increase
(+)
Specific Heat Capacity
Quantity of heat required to change its tempurature by 1C
o
Calorimeter
used to measure heat released/ abosrbed by a physical or chemical process.
Hess's Law of Heat Summation
The enthalpy change of an overall process is the sum of the enthalpy changes.
/\
H +
/\
H
1
=
/\
H
2
A+B=C
Reagent
substance or compound that is added to a system in order to bring about a chemical reaction or is added to see if a
reaction occurs
Limited Reagent
What mass of ___ can be produced from _____
1) Find mole ration of what you NEED (eg 1 mole ----> 2mole
2) Find moles of substances
3) Divide both by the smallest to determine # of moles
4) Compare with need- that which is less than need is limited reagent
Theoretical Yield
1) Balance the reaction and determine the stoichiometry or ratios of reactants to products.
2) Find the number of moles of each starting material used.
3) Determine which reagent is limiting.
4) Calculate the moles of product expected if the yield were 100% based on the limiting reagent. (moles x grams)
5) Calculate the grams of product corresponding to the number of moles expected.
Dilution
Spreading out of solute
Volume of orginal solution + Volume of added solvent = Volume of diluted solution
Indicators
Sustances which undergo a detectable chage at the completeion of a seperate chemical reaction.
Usually Acid-Base indicators undergo a color change at the completion of Acid-Base Titration
Litums
Dye extracted from the inner bark of a south american tree.
Six Forms of Energy
Chem Nursing Lecture
C
hemical
H
eat
E
lectrical
M
echanical
N
uclear
L
ight
All forms of enrgy are...
Interconvertible
Conservative System
When all of the PE can be converted to KE and vice versa
Interconvertiblity
Deforming and object
Overcoming Friction
System in which energy is lost
Nonconservative
Thermodynamics
The study of heat flow or how energy is converted to useful heat and work
Calori
amount of heat when added to 1gram of water cause the temperature to rise 1
o
C
Specific Heat
amount of heat added to specifically 1kilogram of a substance to raise its temperature 1
o
C
Specifies certain conditions
Reversible (rising dropping)
Dulong's Petit's Law
Specific Heat of metals, when multiplied by their molar mass is a constant.
Implies that metals share the same type of bonding.
<-------->
Reversible Reaction
State Functions
Path Independent
STo
o
P
Standard Temperature and Pressure
0
o
C (standard temperature)
1atm (standard pressure
Standard State
The physical state (gas, liquid or solid) in which an element or compount is found at:
25
o
C (room temperature)
1atm (standard pressure)
/\H
Change in Enthalpy
/\H
o
rxn
= Sum of all /\H
o
f
(products) - Sum of all /\H
o
f
(Reactants)
Heat or Enthalpy of any Reaction
Combustion Calorimeter
Measures the heat evolved in a chemical reaction
Author
chiroclown
ID
26010
Card Set
Chemistry Week 3
Description
Test 3
Updated
2010-07-08T05:17:27Z
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