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Law of Conservation of Mass
- "In a chemical reaction, matter is neither created nor destroyed"
- Antoina Lavoisier; observations on combustion.
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Homogenous vs. Heterogenous
Homogenous: a mixture that has the same composition throughout; must be separated by distillation (boiling the mixture so that the more volatile liquid vaporizes and is then recondensed into a separate flask. (koolaid)
Heterogeneous: composition varies from one region to another; separate by filtration. (wet sand)
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Extensive vs. Intensive
Extensive: the value depends on the quantity of matter; extensive properties cannot be used to identify what type of matter something is
Intensive: value independent of the quantity of matter (density)
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Volume equivalencies of a solid
- 1 m3 = 106 cm3
- 1 cm3 = 10-6 m3 = 0.000001 m3
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Commonly measured liquid or gas volume
- 1 L is slightly larger than 1 quart
- 1 L = 1 dm3 = 1000 mL = 103 mL
- 1 mL = 0.001 L = 10-3 L
- 1 mL = 1 cm3
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Common units and their equivalents: Length
- 1 kilometer (km) = 0.6214 mile (mi)
- 1 meter (m) = 39.37 inches (in.)
- 1 meter (m) = 1.094 yards (yd)
- 1 foot (ft) = 30.48 centimeters (cm)
- 1 inch (in.) = 2.54 centimeters (cm) exactly
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Mass: common equivalents
- 1 kilogram (km) = 2.205 pounds (lb)
- 1 pound (lb) = 453.59 grams (g)
- 1 ounce (oz) = 28.35 grams (g)
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Volume: Common Equivalents
- 1 liter (L) = 1000 milliliters (mL)
- 1 liter (L) = 1000 cubic centimeters (cm3)
- 1 liter (L) = 1.057 quarts (qt)
- 1 U.S. gallon (gal) = 3.785 liters (L)
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What did Leucippus and Democritus suggest?
- -All matter was made up of small indestructible particles that they called atomos
- -There were many different kinds of atoms with different shapes and sizes.
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What did Plato and Aristotle suggest?
-All matter was infinitely divisible.
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Law of Definite Proportions
Joseph Proust; All samples of a given compound, regardless of their source or how they were prepared, have the same proportions of their constituent elements.
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Law of Multiple Proportions
- John Dalton
- -When two elements, (call them A and B), form two different compounds, the masses of B that combine with 1 g of A can be expressed as a ratio of small, whole numbers
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Dalton's atomic theory
- Dalton proposed a theory of matter based on it having indivisible particles (atoms) to explain these laws
- 1.) Each element is composed of tiny, indestructible particles called atoms
- 2.) All atoms of a given element has the same mass and other properties that distinguish them from atoms of other elements
- 3.) Atoms combine in simple, whole-number ratios to form molecules of compounds
- 4.) In a chemical reaction, atoms of one element cannot change into atoms of another element
- -they simply rearrange the way they are attached
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Periodic Law
- Mendeleev
- -When the elements are arranged in order of increasing atomic mass, certain sets of properties recur periodically
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Conversions between *F, *C, and K
*C=(*F-32)/1.8
K=*C + 273.15
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Density
-water
-mercury
-ethanol
-lead
- Water = 1.00
- Mercury = 13.55
- Ethanol = 0.789
- Lead = 11.4
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Ionic Bonds
Occur between metals and non-metals; involve the transfer of one atom to another
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Rules for naming ionic compounds
- If cation is:
- -metal with invariant charge = metal name
- -metal with variable charge = metal name(charge)
- -polyatomic ion = name of polyatomic ion
- If anion is:
- -nonmetal = stem of nonmetal name + ide
- -polyatomic ion = name of polyatomic ion
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Hydrogen carbonate (bicarbonate)
HCO3-
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Hydrogen Phosphate
HPO42-
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Dihydrogen Phosphate
H2PO4-
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