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Organic Chemistry Basics
• Organic molecules- molecules that contain carbon and hydrogen
- – If just Hydrogen and Carbon=hydrocarbon
- • Energy-rich bonds (fuel)
- • Non-polar (electrons evenly distribute)
– May also be bound most commonly to oxygen,nitrogen, phosphorus, and sulfur
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Hydrocarbons
- • Carbons can form 4 covalent bonds
- – Carbon-carbon bonds store a lot of energy
- • Major component of
- – Fossil fuel
- – Body fat
- • Shape can be linear, branched, single or double bonds, or rings
- • Completely non-polar
- – Hydrophobic
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Variations in carbon skeletons
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Isomers of organic molecules
• Same number of each atom but different arrangements of those atoms
• Three kinds
– 1. Structural- differ in covalent arrangement of atoms
– 2. Cis-trans- same covalent relationship butdiffers in arrangement on a double bond
– 3. Enantiomers- differ in spatial arrangement around an asymmetric carbon
• L (levo) vs. D (dextro)
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Enantiomers
Differ in spatial arrangement around an asymmetric carbon,resulting in molecules that are mirror images,like left and right hands.
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Functional groups
– Components of an an organic molecule that are reactive
– Attachments that replace the hydrogen on the hydrocarbon skeleton
– Examples you should be able to draw and/or recognize
• Hydroxyl, Carbonyl (including ketones andaldehydes), Carboxyl, Amino, Sulfydryl, Phosphate
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OH
if alone, it will make the organic molecule an alcohol
polar, make an organic compound hydrophilic (water soluble)
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- -contains a carboxyl group C=O
- -found within a hydrocarbon skeleton
- -polar, make a compound hydrophilic
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- -contains a carboxyl group
- -found at the end of a hydrocarbon chain
- -polar, hydrophilic
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- Non-ionic has an OH
- Ionic does not have OH
- -Acidic
- -Ionize reversibly
- -Ionic, hydrophilic
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- -Basic
- -Ionize reversibly
- -ionic, hydrophilic
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- -makes thiols
- -two sulfhydryls can form a covalent bond with each other=disulfide bone
- -polar, hydrophilic (important in protein structure)
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- -acidic
- -ionize resersilby
- -ionic, hydrophilic
- (a component in DNa and ATP)
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