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Combustion
Planned and controlled self sustaining chemical reaction between a fuel and oxygen with the evolution of heat and light.
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Fire
Rapid self sustaining oxidation process that involves heat, light, and smoke in different quantities.
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Fire triangle
Older three sided model used to describe the necessary requirments for fire.
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Fire Tetrahedron
Four sided model describing heat, fuel, oxygen, and chemical reaction need for combustion.
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Free Radicals
Molecular fragment possessing at least one upaired electron.
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Pyrolysis
Break down of a solid into gaseous components when heated.
A.K.A Thermal decompostion
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Spontaneous Combustin
Material self heats to its piloted ignition temp. then ignites.
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Piloted Ignition Temperature
Ignition temp. of a liquid fuel, when heated it will self ignite.
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Particulates
Unburned products of combustion seen in smoke.
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Entrainment
Captured cooler air that replaces the rising heated air surrounding the point of combustion.
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Smoldering Combustion
Absence of flame with presence of hot materials in the surface where oxygen diffuses into the surface of the fuel.
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Acrolein
C3H4O
Strong respiratory irritant produced when polyethylene is heated, or when materials with cellulose smolder.
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Hydrogen Chloride
HCI
- Colorless but pungent
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- irritating gas givin off during thermal decomposition of materials that contain chlorine.
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Hydrogen Cyanide
HCN
Colorless, almond odor
20X more toxic than CO
Asphyxiant can be absorbed through skin
Produced from combutsion of natural materials (wool, silk), or materials containing urea.
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Carbon Dioxide
CO2
Colorless, odorless
Nonflammable gas
Can cause asphyxia by eliminating oxygen from confined space.
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Nitrogen Oxides
NO2 and NO
Smoke is a reddish brown color
Can have delayed symptoms
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Phosgene
COCI2
Highly toxic, colorless gas
Disagreeable odor of musty hay
Symptoms delayed several hours from exposure
Produced when freon or refrigerants come into flame contact.
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Stoichiometry of Reaction
Proportion of fuel to oxygen and the resulting end products.
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Stoichiometry
Ideal burning situation where there is perfect balance of fuel and oxygen.
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Flamming Coumbustion
Exothermic chemical reaction with flames occuring between a substance and oxygen.
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Diffuse Flamming
Combustion process where the flames are part of the actual process.
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Class A Fire
Ordinary combustibles.
Extinguished by water.
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Class B Fires
Flammable liquids.
Extinguished by removing oxygen supply and cooling.
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Class C Fire
Electrical fire
Extinguished by cutting of power.
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Class D Fire
Combustible metals
Extinguish by specific foam mixture for different metals.
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Class K Fire
Cooking Oil
Extinguish by dry or wet chemical depending on sopanification.
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Saponification
Process of chemically converting fatty acid to sopa or foam.
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Fire Stages
Ignition
Growth
Fully developed
Decay
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Incipient Stage
Point in which the 4 components of the fire tetrehedron come together and materials reach there ignition temp.
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Growth Stage
Fire increases fuel consumption and heat generation.
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Fully Developed Stage
Maximum Fuel consumption and heat occurs.
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Flame Over
Flames travel up and long uburned gases during fire development.
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Flashover
Sudden event that occurs when all contents of a confined space reach there ignition temperature and ignite simultaneously.
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Backdraft
Violent reignition of closed container that has consumed all the oxygen within the container when new oxygen is introduced.
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Decay Stage
Fire has consumed all available fuel and temperaure begins to decrease.
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Compartmentation
Used in high rise buildings to provide a safe environment within the structure where persons can be protected from fire.
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Stack Effect
Temp. difference between inside of a bulding and the outside of the building
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Relative Humidity
Ratio of moisture in a given volume to the amount that volume would contain if saturated.
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Law of Latent Heat of Vaporization
Heat that is absorbed when one gram of liquid is transformed into vapor at the boiling point under one atmospheric pressure.
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