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E&S:Lecture 12
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Biofuels are created through....
photosynthesis
the chlorophyll pigments absorbs photons at _____and _____wavelengths
blue and red
Photosynthesis equation
6CO2 + 6H2O +hv = C6H12O6 + 6O2
Plants can't take in CO2 for photosynthesis without
loosing water vapor, which saturates their pores when closed
Plants in dry climates
1.Can't afford to lose water
-let in very little CO2
-grow very slowly
The net photosynthetic efficiency of most ecosystems
1%
the residence time for surface organic carbon
20 years
Carbon cycle steps
1. Plants and ocean remove CO2 from atmosphere
2. animals eat plants and release waste
3. Plant and animal organic matter get buried underground
4. after millions of years, turn into fossil fuels
5. animals respire and release CO2 and fossil fuels burned
"Dry" Biomass compostion
1.Cellulose
2.Hemi-Cellulose
3.Lignin
4.Other
: oils, sugars, minerals
Cellulose
1.Linear chain of thousands of linked glucose units
-only digestible by bacteria (termites)
Hemi-Cellulose
1. Non-starch component of plants
2. only digestible by plants
Lignin
1. Fills the spaces between cell wals to make them stiff and water proof
2. Common in wood
3. Only digestible by bacteria
Biomass energy
16-20 MJ/kg
Diesel fuel can be produced from
1. Rapeseed
2.Soybean oils
3.Animal fats
4. Waste
Production process of Biodiesel
1. Removing water and contaminants
2. Treat with a solution of methanol and KOH
3. Purify
why is Biodiesel superior to conventional diesel fuel?
1.Low sulfur content
2. Pleasant aroma
Biogas
1. Anaerobic decomposition of organic matter can be a source of methane gas
Biogas Reaction
C6H12O6 ------3CO2 + 3CH4
Fermentation
1. Incomplete oxidation of organic compounds
-electron acceptor is another organic molecule
Examples of fermentation
1.Fermentation of sugar by yeast or bacteria to make ethanol (beer, wineetc.)
2. Creation of lactic acid in animal muscles when oxygen supply is low
3. Anaerobic digestion of organic by bacteria to produce methane and hydrogen gas(cows)
Fermentation reactions are generally
anaerobic and exothermic, thus producing their own heat
Ethanol power
31.1MJ/kg
E10 or less is
Gasohol
E85
Highest mixture sold in USA
What proof is pure distilled ethanol?
190
Issues with Ethanol
1.minimal to negative net energy production
2.displaces food production and water resources
3.increases corn prices
Future of ethanol
1. Lies in cellulosic ethanol
-Enzymes convert cellulose----sugar(fermented)----ethanol
-can be harvested from grass
-requires no cultivation or irrigation
Algal fuels
1.Oils and fuels produced by algae
Issues with Algal fuels
1.High infrastructure costs
Process:Algal fuel production
1.Grow algae
2.Starve it of nutrients
3.Break alage open
4. Use solvents to separate the fats from sugars
5. Evaporate solvent
6. Transform fat to biodiesel
Author
dante01
ID
158128
Card Set
E&S:Lecture 12
Description
study
Updated
2012-06-11T03:31:57Z
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