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Alkene + Ozone & Hydrogen Peroxide
Carboxyllic Acid
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CO2 + Grignard
Carboxyllic Acid
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Anhydride + H2O
Carboxyllic Acid
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Ester + Water/H+ and Heat
Carboxyllic Acid
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Nitrile + Water/H+ and Heat
Carboxyllic Acid
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Carboxyllic Acid + CH2N2
Methyl Ester
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Carboxyllic Acid + Acid & R-OH & Heat
Ester
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Carboxyllic Acid + SOCl2
Acid Halide
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Carboxyllic Acid + LAH
Primary Alcohol (Cleaves off =O)
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Ester + Acid & R-OH & Heat
Transesterification
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Ester + NaOH
Carboxylate Salt
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Acid Halide + NaOR or R-OH + Pyridine
Ester
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Ester + LAH
Primary Alcohol
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Acid Halide + Gilman
Ketone
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Acid Halide + Water
Carboxyllic Acid
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Acid Halide + 1,2, amine or NH3 (2 mol or 1 w/pyridine)
Amide
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Acid Halide + NaOCOR or HO-COR & Pyridine
Anhydride
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Amide + NaOH
Carboxylate Salt
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What is the Hoffman Rearrangement?
When an Amide reacts with Sodium Hydroxide, Br2 and is heated, it forms an Amine MINUS 1 CARBON from the original reagent.
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Amide + LAH
Amine (Cleaves Off =O)
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Dehydrate Alcohol into Alkenes?
Concentrated H+ and HEAT
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How could you change a carboxyl group into an Alkene?
Wiggins reagent Ph3P=R attaches its R group in place of the Oxygen.
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What does a Carbynol Reaction do?
:C-C triple bond can reduce a ketone to an alcohol.
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What does Jones Reagent do?
Jones reagent turns Alcohols into Carboxylic Acids OR Ketones.
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Which reagent would one use for Radical Halogenation?
Br2 plus hv
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Where does the halogen go in a Radical Halogenation?
Chlorine is not selective. Bromine, on the other hand, prefers secondary carbons.
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How could one convert R-OH -> R-O-R
Williamson Synthesis
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How could one convert an Alkene to an alcohol?
- Water and Concentrated H+ (M)
- Oxy Mercuration Demurcuration (M)
- or Hydroboration (AM)
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How could one convert an Alkene to R-X
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How would one convert an alcohol to alkyl halide?
- PX3
- SOX2 and Pyridine
- CBR4 and PPH3
- HX
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What does PCC reagent do?
Converts Alcohols into Aldehydes OR Ketones
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What does DMP reagent do?
Converts Alcohols in Aldehydes OR Ketones
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How would you convert an aldehyde or ketone into an alcohol?
NaBH4
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