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Tie line
- line constructed when calculating phase
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Eutectic Reaction
involves one liquid and two solids
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Eutectoid Reaction
involves a single phase and two phase solid
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Cementite
(Fe3C) Metal carbide, ceramic
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Pearlite
(α+Fe3C) lamellar structure
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Bainite
(α+Fe3C) carbide plates
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Widmanstatten Ferrite
- α needles with C buildup in
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Spheroidization
When left at elevated temperatures for extended amounts of time the lamellar pearlite begins to form globs, and as time continues, the particles will get larger
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Metallic Bonding
sharing of valence electrons across the entire molecule
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Covalent Bonding
sharing of valence electrons in a localized region
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Abrasive Wear
Loss of material from a surface by the gouging-out of channels by hard particles lying etween the two surfaces being sheared past one another
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Adhesive Wear
Closely related to the primary cause of friction; invloves the transfer of material from one surface to another when the surfaces are being sheared past one another while a force is being applied normal to the interface. It is caused by cold welding across the touching asperities on the respective surfaces. The normal force acts to flatten the asperities and to increase the contact area over which cold welding can occur.
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Boundary Lubrication
This occurs when a solid or semi-solid material lies in an interface and reduces the resistance to shear between the interfaces.
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Hydrodynamic Lubrication
Same as boundary lubrication but at high velocities that gives it a much lower coefficient of friction.
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Hardenibility
The capacity of a steel to be transformed to martensite, instead of the diffusion-controlled transformed products, ferrite and cementite.
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Case Hardening
The hardening of the outside surfaces of a steel component by introducing extra amounts of carbon and/or nitrogen by diffusion at an elevated temperature, either to cause high-carbon martensite to form upon quenching, or to form a fine dispersion of alloy nitrides, and thereby to make the surface harder and more resistant to wear.
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Carburization
This is a surface hardening, or case hardening, treatment carried out by heating a steel in an atmosphere of H2/CH4 or CO/CO2, that deposits carbon on the surface. Inward diffusion of carbon raises the carbon content of the surface regions so that high-carbon martensite is formed when the steel is quenched.
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Annealing
Heating a cold-worked metal to remove the effects of strain hardening. It comprises the processes of recovery, recrystallization, and grain growth.
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Tempering
The heat treatment of steel that has been austenitized and quenched to form martensite. It involves heating in the ferrite + carbide region of the phase diagram (below the eutectoid temperature) to promote the decomposition of the metastable martensite. Done to improve toughness at the sacrifice of hardness.
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Toughness
Measure of the resistance of a material to the propagation of a crack when stress is applied
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Hardness
Usually means the resistance of a material to plastic deformation
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Precipitation hardening
A mechanism of hardening that involves the formation of a finely dispersed array of very small particles of a second phase that act as a strong barrier to dislocation motion. The alloy is solution treated and quenched, then aged at a temperature in the two-phase region.
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Homogeneous nucleation
The nucleation of a second phase in a supersaturated parent phase at random locations throughout the parent phase, without regard for the presence of any structural defects that could enhance the nucleation rate.
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Heterogeneous nucleation
The nucleation of a second phase in a supersaturated parent phase not randomly, but on structural defects that act to lower the energy barrier for this nucleation, often by providing an existing interphace on which the new phase can form. Much less undercooling is required.
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Entropy
The amount of disorder in a system.
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Enthalpy
H, the sum of the internal energy, E, and the energy due to the pressure times the volume.
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Activation Energy
the energy that must be supplied to a system in metastable equilibrium to allow it to pass to a state of lower energy.
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Ductility
the ability of a material to deform plastically without fracturing
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Strength
the maximum nominal stress a material can sustain.
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Octahedral site
In a Bcc, the site that produces the minimum overall strain energy in the lattice.
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Fatigue
failure due to a dynamic and fluctuating stress in a structure.
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Fatigue limit
A value of stress below which a material will not fail due to fatigue and where, theoretically, a material can endure infinite cycles.
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Component
participating elements
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Phase
physically and chemically distinct region of material
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Solution
solid solution, single phase (syrup)
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Mixtures
more than one phase (syrup + sugar)
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Solubility Limit
Max concentration for which only a single phase solution occurs
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Brazing
A technique of joining two solid pieces by melting a filler metal and letting it flow into the crevice between the two pieces. Can occur at temperatures above 450 C.
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Soldering
A technique of joining two solid pieces by melting a filler metal and letting it flow into the crevice between the two pieces. Can occur at temperatures below 450 C.
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Contact Angle
The measure of a liquid on a solid surface to determine how well a liquid "wets" a surface. Depends on the energies of the interactions of the phases.
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Casting
A process that involves the melting of a metal or alloy and pouring the molten metal into a mold in which it solidifies, taking the shape of the mold.
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