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a hydrocarbon that contains one or more carbon-carbon double bonds
C=C
Alkene
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a hydrocarbon that contains one or more carbon-carbon triple bonds C = C
Alkyne
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alkenes taht contain 2 double bonds
alkadienes
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alkenes taht contain 3 double bonds
alkatrienes
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alkenes taht contain several double bonds
polyenes
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-non polar
-only attractive forces between their molecules are london dispersion forces
-physical properties are similiar to alkanes with same carbon skeleton
-insoluble in water
-soluable in one another
- float on water
Alkenes and Alkynes
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If a molecule has n double bonds about which cis-trans isomerism is possible then 2n isomers are possible.
CH3-CH=CH-CH=CH-CH2-CH3
22=4
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four carbon chain with a carbon coming off of #2 Carbon
Terpenes
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most alkene addition reactions are
- exothermic
- (the products are more stable, lower in energy, than the reactants.
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H adds to the less substituted carbon and X(cl,br,etc) adds to the more substituted carbon.
Less Cs More Hs, add H
More Cs, less Hs, add X
Markovnikov's rule
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- low density weaker (high branched do not pack well)
- trash bags
Low-density polyethylenes (LDPE)
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high density, stronger (only minimal chain branching)
- high melting point, (bottles, squeeze jugs)
High Density Polyethylene (HDPE)
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nCH2=CH2
ethylene n means it continues
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any long chain molecule synthesized by bonding together many single parts
polymer
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single part that used in polymer
monomer
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a hydrocarbon that contains one or benzene-like rings
aromatic compound
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a term used to describe aromatic compounds
arene
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equals stability
the length of a carbon-carbon bond in benzene is midway between that of a carbon-carbon single bond and a double bond. (in between)
resonance
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a hydrocarbon that contains two or more benzene rings, with each pair of rings sharing two adjacent carbon atoms.
polynuclear aromatic hydrocarbon (PAH)
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the degree is determined by how many Cs are attached to the + C of the double bond
carboncation
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addition of water
hydration
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the catalye foR hydration is most commonly
H2SO4
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the reagent for hydration is H2O dont forget that in the second step it is the water molecule, and then the THIRD STEP is called the loss of H+ which is called
deprotonation
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species containing one oxygen atom with 3 bonds to it and bearing a positive charge
oxonium ion
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adding HCl is called
hydrochlorination
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adding Br2 is called
bromination
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adding H2 is called
hydrogenation or reduction
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the catalyze or organic solvent used in adding Cl2 and Br2 is
CH2Cl2
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the reagent for adding brominatoin or chlorination is
Br2 or Cl2
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the reagent in hydrogenation is
H2
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The catalyze in hydrogenation is
Pd, Pt, or Ni
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- top is ortho (o)
- bottom left is para (p)
- bottom right is meta (m)
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a hydrocarbon that contains 2 or more benzene rings, with each pair of rings sharing two adjacent carbon atoms.
PAHs polynuclear aromatic hydrocarbon
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by far the most characteristic reaction of aromatic compounds is substitution at a ring carbon. this is called
aromatic substitution
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in Halogenation reaction of benzene the catalyze is
FeCl3
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in halogenation of benzene the reagent is
- Cl2, Br2
- the H and the halogen switch places, for product +H(X)
- -H +Cl2 > -Cl + HCl
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in Nitration
water always becomes a product!!!
the catalyze is
H2SO4
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in Nitration of Benzene the reagent is
- HNO3 - H + HNO3 > -NO2 + H2O
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In Nitration the nitro group can be reduced to a primary aminio by catalytic reduction using
H2 as a reagent and a transition-metal as a catalyze
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Nitration with nitro reduction
- - NO2 + 3H2 > -NH2 +2H2O
- any benzene with nitro taht with H, Ni becomes NH2 as a product
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Sulfonation : heating an aromatic compound with concentrated H2SO4 results in
an arenesulfonic acid
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the functional group of a phenol is a
hydroxyl (-OH) group bonded to a benzene ring
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weak acids, insoluble in water, but react with a strong base, to form water-soluable salts. Do NOT react with weak bases
phenols
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oxidation requiring oxygen and NO other reactants.
the reaction converts an R-H group to an R-O-O-H
-radical chain reaction
Autoxidation
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an atom of molecule with an unpaired electron C*
radical
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removal of an H atom by light or heat
Product is a
carbon radical
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hydroperoxides
- - are unstable
- - nature has developed a series of defenses against these, including the phenol vitamin E
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is a natural antioxidant
BHt and BHA are synthetic antioxidants
radical scavengers, they form stable radicals and break the cycle of chain propagation steps.
Phenols Vitamin E
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